167479

Chloroacetone

95%

• Sinónimos: 1-Chloropropan-2-one
• Fórmula lineal: ClCH₂COCH₃
• Número de CAS: 78-95-5
• Peso molecular: 92.52
• Beilstein/REAXYS Number: 605369
• EC Number: 201-161-1
• MDL number: MFCD00000936
• UNSPSC Code: 12352100
• PubChem Substance ID: 24850211
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: 95%
• contains: ~0.1% Drapex 39 as stabilizer
• impurities: ~5% 1,1-dichloroacetone and/or mesityl oxide
• refractive index: n20/D 1.432 (lit.)
• bp: 120 °C (lit.)
• mp: −44.5 °C
• solubility: alcohol: miscible; chloroform: miscible; diethyl ether: miscible
• density: 1.162 g/mL at 25 °C (lit.)
• functional group: chloro; ketone
• storage temp.: 2-8°C
• SMILES string: CC(=O)CCl
• InChI: 1S/C3H5ClO/c1-3(5)2-4/h2H2,1H3
• InChI key: BULLHNJGPPOUOX-UHFFFAOYSA-N

Descripción

General description

Direct aldol reaction of chloroacetone with of 4-nitrobenzaldehyde catalyzed by L-proline amides has been investigated.

Application

Chloroacetone was used in the synthesis of double-chain nonionic surfactants with an acid decomposition function via acid-catalyzed condensation with fatty alcohols (octyl, decyl and dodecyl). It was also used in the synthesis of meso-tetramethyl tetrakis-(4-phenoxy acetone)calix[4]pyrrole.

Información de seguridad

• pictograms: GHS02,GHS06,GHS05,GHS09
• signalword: Danger
• hcodes: H226,H301,H310 + H330,H314,H335,H410
• pcodes: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 95.0 °F - closed cup
• flash_point_c: 35 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter