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Merck

45708

Ziram

PESTANAL®, analytical standard

Synonym(s):

Zinc dimethyldithiocarbamate, Dimethyldithiocarbamic acid zinc salt, Ziram

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About This Item

Linear Formula:
(CH3)2NCSSZnSCSN(CH3)2
CAS Number:
137-30-4
Molecular Weight:
305.82
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329756917
EC Number:
205-288-3
Beilstein/REAXYS Number:
3707008
MDL number:
MFCD00064797

Key Documents

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Product Name

Ziram, PESTANAL®, analytical standard

InChI key

DUBNHZYBDBBJHD-UHFFFAOYSA-L

InChI

1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2

SMILES string

CN(C)C(=S)S[Zn]SC(=S)N(C)C

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

reaction suitability

reagent type: catalyst
core: zinc

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

248-257 °C (lit.)

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-8°C

Quality Level

100

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Ziram may be used as an analytical reference standard for the quantification of the analyte in environmental samples, grains, and vegetable samples using different analytical techniques.

General description

Ziram is a fungicide, widely used for the protection of vegetable crops, seed foliage and fruits. It is also employed in rubber industry as an antioxidant and vulcanization accelerator.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

target_organs

Liver,Blood, Respiratory system

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM4022
BCCH8153
BCBW3982
BCBS8321V

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Determination of ziram in vegetable samples by square wave voltammetry
Qui P, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 19(11), 1337-1340 (2008)
Spectrophotometric determination of ziram (dithiocarbamate fungicide) by thiocyanate and rhodamine 6G method
Mathew L, et al.
Talanta, 42(1), 41-43 (1995)
Josiane P Lafleur et al.
Lab on a chip, 12(22), 4651-4656 (2012-07-25)
Conventional methods of environmental analysis can be significantly improved by the development of portable microscale technologies for direct in-field sensing at remote locations. This report demonstrates the vast potential of gold nanoparticle-based microfluidic sensors for the rapid, in-field, detection of
Emanuela Corsini et al.
Toxicology and applied pharmacology, 212(2), 89-98 (2005-08-23)
Mancozeb, a polymeric complex of manganese ethylenebisdithiocarbamate with zinc salt, is widely used in agriculture as fungicide. Literature data indicate that ethylenebisdithiocarbamates (EBDTCs) may have immunomodulatory effects in humans. We have recently found in agricultural workers occupationally exposed to the
Thyneice R Taylor et al.
Toxicology mechanisms and methods, 21(8), 577-584 (2011-08-24)
Human natural killer (NK) cells are central in immune defense with their ability to lyse tumor cells and virally infected cells. Tumor formation and viral infection may increase if NK cytotoxic function is disrupted. Ziram (zinc dithiocarbamate) is used as
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