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90885

Sigma-Aldrich

3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-1-octanethiol

97%

Synonym(s):

1H,1H,2H,2H-Perfluoro-1-octanethiol, 1H,1H,2H,2H-Perfluorooctyl mercaptan

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About This Item

Linear Formula:
CF3(CF2)5CH2CH2SH
CAS Number:
34451-26-8
Molecular Weight:
380.17
MDL number:
MFCD00792427
UNSPSC Code:
12352105
PubChem Substance ID:
57653414
NACRES:
NA.22

Quality Level

100

Assay

≥96.5% (GC)
97%

form

liquid

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCS

InChI

1S/C8H5F13S/c9-3(10,1-2-22)4(11,12)5(13,14)6(15,16)7(17,18)8(19,20)21/h22H,1-2H2

InChI key

GTPHVVCYEWPQFE-UHFFFAOYSA-N

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General description

3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-1-octanethiol is a fluorinated alkanethiol, which is also known as 1H,1H,2H,2H-Perfluorooctanethiol.

Application

3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-1-octanethiol is used to differentiate the effect on the work function and surface wetting for silver. Additionally, it can be used as a starting material to synthesize F-alkyl aroxysulfonyl carbamates and thiocarbamates.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis of F-alkyl N-sulfonyl carbamates and thiocarbamates
M Beji
Journal of Fluorine Chemistry, 99, 17-24 (1999)
Concomitant tuning of metal work function and wetting property with mixed self-assembled monolayers
CY Chen
Organic Electronics, 12, 148-153 (2011)
Guangyu Rong et al.
Science advances, 6(33), eaaz1774-eaaz1774 (2020-08-28)
Cytosolic delivery of peptides remains a challenging task owing to their susceptibility to enzymatic degradation and the existence of multiple intracellular barriers. Here, we report a new strategy to address these issues by decoration of a fluorous tag on the
Yong Jin Jeong et al.
ACS nano, 12(8), 7701-7709 (2018-07-20)
Photoresponsive transistor memories that can be erased using light-only bias are of significant interest owing to their convenient elimination of stored data for information delivery. Herein, we suggest a strategy to improve light-erasable organic transistor memories, which enables fast "photoinduced

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