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703516

Sigma-Aldrich

Zinc chloride solution

greener alternative

1.9 M in 2-methyltetrahydrofuran

Synonym(s):

Dichlorozinc

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About This Item

Linear Formula:
ZnCl2
CAS Number:
7646-85-7
Molecular Weight:
136.30
MDL number:
MFCD00011295
UNSPSC Code:
12352302
PubChem Substance ID:
329762045
NACRES:
NA.23

form

liquid

reaction suitability

reagent type: catalyst
core: zinc

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

1.9 M in 2-methyltetrahydrofuran
25 % (w/w)

density

1.07 g/mL at 25 °C

greener alternative category

, Aligned

SMILES string

Cl[Zn]Cl

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Lewis acid in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Signal Word

Danger

Hazard Statements

H225,H302,H314,H335,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

10.4 °F - closed cup - Solvent

Flash Point(C)

-12 °C - closed cup - Solvent

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Zinc chloride anhydrous, free-flowing, Redi-Dri™, ACS reagent, ≥97%

Sigma-Aldrich

746355

Zinc chloride

Zinc chloride anhydrous, free-flowing, Redi-Dri™, reagent grade, ≥98%

Sigma-Aldrich

793523

Zinc chloride

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Jessica Duprez et al.
PloS one, 7(10), e46831-e46831 (2012-10-12)
Rat pancreatic islet cell apoptosis is minimal after prolonged culture in 10 mmol/l glucose (G10), largely increased in 5 mmol/l glucose (G5) and moderately increased in 30 mmol/l glucose (G30). This glucose-dependent asymmetric V-shaped profile is preceded by parallel changes
Russell E Carter et al.
Journal of neurochemistry, 125(5), 673-684 (2013-03-19)
Spreading depolarization (SD) is a feed-forward wave that propagates slowly throughout brain tissue and recovery from SD involves substantial metabolic demand. Presynaptic Zn(2+) release and intracellular accumulation occurs with SD, and elevated intracellular Zn(2+) ([Zn(2+) ]i ) can impair cellular
Mayank Anand Gururani et al.
Plant science : an international journal of experimental plant biology, 198, 7-16 (2012-12-04)
Manganese stabilizing protein (MSP) is an important component of the Photosystem II (PSII) oxygen evolving complex. In our previous work, transgenic potato plants with reduced expression of MSP (MSP-As) were developed and their physiological and biochemical responses were studied. In
Elwin Molenbroek et al.
Dalton transactions (Cambridge, England : 2003), 42(8), 2973-2984 (2012-12-22)
In this work, the complexation of the bapbpy ligand to zinc dichloride is described (bapbpy = 6,6′-bis(2-aminopyridyl)-2,2′-bipyridine). The water-soluble, colorless complex [Zn(bapbpy)Cl]Cl·2H2O (compound 2·H2O) was synthesized; its X-ray crystal structure shows a mononuclear, pentacoordinated geometry with one chloride ligand in
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