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Sigma-Aldrich

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide

≥98.0% (T)

Synonym(s):

BMP-BTI

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About This Item

Empirical Formula (Hill Notation):
C11H20F6N2O4S2
CAS Number:
223437-11-4
Molecular Weight:
422.41
MDL number:
MFCD07784447
UNSPSC Code:
12352100
PubChem Substance ID:
57649870
NACRES:
NA.22

description

electrochemical window -3.0 - +2.4 V

Assay

≥98.0% (T)

impurities

≤0.2% water

viscosity

548 stokes

mp

-18 °C

SMILES string

CCCC[N+]1(C)CCCC1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C9H20N.C2F6NO4S2/c1-3-4-7-10(2)8-5-6-9-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3-9H2,1-2H3;/q+1;-1

InChI key

HSLXOARVFIWOQF-UHFFFAOYSA-N

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General description

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide is a room temperature ionic liquid (RTIL) with a wide electrochemical window (5.5V) and high viscosity, making it a useful candidate in electrochemical energy applications.

Application

BMP-BTI has been used as a derivatization media for dimethyl sulfate (DMS) with dibenzazepine.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Activity coefficients at infinite dilution for organic solutes dissolved in three 1-alkyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide ionic liquids bearing short linear alkyl side chains of three to five carbons
Mutelet, Fabrice, et al.
Journal of Chemical and Engineering Data, 58.8, 2210-2218 (2013)
In situ STM investigation of gold reconstruction and of silicon electrodeposition on Au (111) in the room temperature ionic liquid 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
Borisenko, N., Sh Zein El Abedin, and F. Endres
The Journal of Physical Chemistry B, 110.12, 6250-6256 (2006)
Charge carrier dynamics and relaxation in (polyethylene oxide-lithium-salt)-based polymer electrolyte containing 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide as ionic liquid
Karmakar, A., and A. Ghosh.
Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics, 84.5, 051802-051802 (2011)
Additive free electrodeposition of nanocrystalline aluminium in a water and air stable ionic liquid
El Abedin, S. Zein, et al.
Electrochemical Communications, 7.11, 1111-1116 (2005)
Ionic Liquids for Energy Storage Applications
Stenger-Smith JD and Irvin JA.
Material Matters, 4(4), 103-103 (2009)
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Articles

Ionic Liquids for Energy Storage Applications

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Ionic Liquids for Energy Storage Applications

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Ionic Liquids for Energy Storage Applications

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

Ionic Liquids for Energy Storage Applications

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

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