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234826

Sigma-Aldrich

Bis(cyclopentadienyl)titanium(IV) dichloride

97%

Synonym(s):

Cp2TiCl2, Dichlorobis(1,3-cyclopentadiene)titanium, Dichlorodicyclopentadienyltitanium, Dichlorotitanocene, Cp2TiCl2, Di(cyclopentadienyl)titanium(IV) dichloride, Titanocene dichloride

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About This Item

Empirical Formula (Hill Notation):
C10H10Cl2Ti
CAS Number:
1271-19-8
Molecular Weight:
248.96
EC Number:
215-035-9
MDL number:
MFCD00003723
UNSPSC Code:
12161600
PubChem Substance ID:
24854058
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

100

Assay

97%

reaction suitability

core: titanium
reagent type: catalyst

mp

260-280 °C (dec.) (lit.)

density

1.6 g/mL at 25 °C (lit.)

SMILES string

Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

XKLWATAZDMHTSH-UHFFFAOYSA-L

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Application

One-pot synthesis of α-methylene-γ-butyrolactones from benzaldehydes and bromomethylacrylates.[1]

Signal Word

Danger

Hazard Statements

H318,H335,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBK7215
STBK4429
STBK1876
STBJ2898
STBH8972

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Samaresh Jana et al.
The Journal of organic chemistry, 70(20), 8252-8254 (2005-11-10)
[Chemical reaction: see text] A radical based Wagner-Meerwein-type rearrangement has been observed in camphoric systems. The radical was generated from the epoxide using Cp2TiCl as the radical source. The radical initiator Cp2TiCl was prepared in situ from commercially available Cp2TiCl2
Sumit Saha et al.
The Journal of organic chemistry, 76(17), 7229-7234 (2011-07-29)
Titanocene(III) chloride (Cp(2)TiCl) mediated radical induced allylation of aldimines for the preparation of homoallyl amines is described. The radical was generated from the allyl bromide using Cp(2)TiCl as the radical source. Formal synthesis of C(4)-C(5')-linked 4'-deoxy aza-disaccharide is demonstrated and
[Determination of organometallic antitumor crude drug titanocene dichloride by NP-HPLC].
Yunlan Li et al.
Se pu = Chinese journal of chromatography, 25(2), 282-283 (2007-06-22)
Ramón Hernández et al.
Toxicology in vitro : an international journal published in association with BIBRA, 24(1), 178-183 (2009-09-24)
Replacement of the ancillary ligand in titanocene dichloride by amino acids provides titanocene species with high water solubility. As part of our research efforts in the area of titanium-based antitumor agents, we have investigated the cytotoxic activity of Cp(2)TiCl(2) and
Tetrahedron Letters, 48, 3205-3205 (2007)
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