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Acétate d'ammonium

Ammonium acetate

LiChropur, eluent additive for LC-MS

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About This Item

Formule linéaire :
CH3CO2NH4
Numéro CAS:
Poids moléculaire :
77.08
Beilstein:
4186741
Numéro CE :
Numéro MDL:
Code UNSPSC :
12000000
eCl@ss :
39021908
ID de substance PubChem :
Nomenclature NACRES :
NB.21
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Qualité

eluent additive for LC-MS
LiChropur

Niveau de qualité

Agence

suitable for ASTM® 7968
suitable for ASTM® 7979
suitable for DIN 38407-42
suitable for EPA 1633
suitable for EPA 533
suitable for EPA 537.1
suitable for EPA 8327
suitable for EPA ACB B21-02
suitable for EPA ACB B23-05b
suitable for GB 31604.35-2016
suitable for GB 5009.253-2016
suitable for ISO 21675 2019
suitable for ISO 25101
suitable for ISO/CEN 15968-2010

Conformité réglementaire

suitable for FDA C-010.02

Essai

≥99.0% (calc. on dry substance, T)

Forme

solid

Technique(s)

LC/MS: suitable

Impuretés

insoluble matter, passes filter test
≤1% water

Résidus de calcination

≤0.01% (as SO4)

pH

6.2-7.5 (25 °C, 1 M in H2O)

Pf

110-112 °C (dec.) (lit.)

Solubilité

H2O: 1 M at 20 °C, clear, colorless

Traces d'anions

chloride (Cl-): ≤5 mg/kg
nitrate (NO3-): ≤10 mg/kg
sulfate (SO42-): ≤10 mg/kg

Traces de cations

Al: ≤1 mg/kg
As: ≤0.1 mg/kg
Ba: ≤1 mg/kg
Bi: ≤1 mg/kg
Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤5 mg/kg
Li: ≤1 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Mo: ≤1 mg/kg
Na: ≤5 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Sr: ≤1 mg/kg
Zn: ≤1 mg/kg

Chaîne SMILES 

N.CC(O)=O

λ

1 M in H2O

Absorption UV

λ: 260 nm Amax: ≤0.015
λ: 280 nm Amax: ≤0.010

Adéquation

passes test for LC-MS

InChI

1S/C2H4O2.H3N/c1-2(3)4;/h1H3,(H,3,4);1H3

Clé InChI

USFZMSVCRYTOJT-UHFFFAOYSA-N

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Description générale

L′acétate d′ammonium se présente sous la forme de cristaux blancs. Il est préparé à partir d′acide acétique et d′ammoniac par neutralisation à pH 7,0. Il est couramment utilisé en chimie analytique, dans les médicaments et pour la teinture des textiles.[1]

Application

L′acétate d′ammonium a servi à préparer des éluants pour UPLC-MS/MS et HPLC-MS/MS afin de comparer l′effet de matrice de neuf composés pharmaceutiques dans des échantillons environnementaux aqueux.[2] Il a également été employé comme additif pour améliorer la détection de phosphopeptides par MALDI-MS.[3]

Produits recommandés

Découvrez LiChropur, la gamme de réactifs idéale pour vos analyses par HPLC ou LC-MS

Informations légales

ASTM is a registered trademark of American Society for Testing and Materials
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Application

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type N95 (US)


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Certificats d'analyse (COA)

Lot/Batch Number

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Enhanced detection of phosphopeptides in matrix-assisted laser desorption/ionization mass spectrometry using ammonium salts.
Asara JM, Allison J.
Journal of the American Society For Mass Spectrometry, 10(1), 35-44 (1999)
Dale L. Perry
Handbook of Inorganic Compounds, 17-17 (1995)
J M Asara et al.
Journal of the American Society for Mass Spectrometry, 10(1), 35-44 (1999-01-15)
Matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS) has been used successfully to detect phosphorylation sites in proteins. Applications may be limited by the low response of phosphopeptides compared to nonphosphorylated peptides in MALDI MS. The addition of ammonium salts to
Comparison of matrix effects in HPLC-MS/MS and UPLC-MS/MS analysis of nine basic pharmaceuticals in surface waters.
Van De Steene JC, Lambert WE.
Journal of the American Society For Mass Spectrometry, 19(5), 713-718 (2008)
Jet C Van De Steene et al.
Journal of the American Society for Mass Spectrometry, 19(5), 713-718 (2008-03-18)
When developing an LC-MS/MS-method matrix effects are a major issue. The effect of co-eluting compounds arising from the matrix can result in signal enhancement or suppression. During method development much attention should be paid to diminishing matrix effects as much

Articles

This study demonstrates the impact of various mobile phase modifiers on the separation; formate modifiers outperform acetate in terms of MS signals (or sensitivity) and chromatographic resolution.

LC-MS method separates 32 PFAS compounds in drinking water following EPA methods 533, 537, and 537.1. EPA 8327.

LC-MS method separates 32 PFAS compounds in drinking water following EPA methods 533, 537, and 537.1. EPA 8327.

Learn about the separation of several charge variants of two monoclonal antibodies, NISTmAb and Infliximab, using a polymeric cation exchange column and MS-compatible mobile phases.

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Protocoles

Strat-M® synthetic membrane mimics the human skin for In-vitro permeation testing (IVPT) of topical and transdermal formulations

Chromatograms

application for UHPLCapplication for HPLC

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. under what conditions should you store ammonium acetate? ambient temperature with low relative humidity or 2-6 degrees in a fridge with high relative humidity- given that it is hygroscopic

    1 answer
    1. This product is to be stored at room temperature. Although this material is hygroscopic, desiccation is not required if the bottle is securely sealed.

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