52630

Hexaméthyldisiloxane

puriss., ≥98.5% (GC)

• Synonyme(s) : HMDSO
• Formule linéaire : (CH₃)₃SiOSi(CH₃)₃
• Numéro CAS: 107-46-0
• Poids moléculaire : 162.38
• UNSPSC Code: 12352103
• NACRES: NA.22
• PubChem Substance ID: 329757863
• EC Number: 203-492-7
• Beilstein/REAXYS Number: 1736258
• MDL number: MFCD00008265

Propriétés

• vapor density: >1 (vs air)
• Quality Segment: 200
• grade: puriss.
• assay: ≥98.5% (GC)
• form: liquid
• refractive index: n20/D 1.377
• bp: 101 °C (lit.)
• mp: −59 °C (lit.)
• density: 0.764 g/mL at 20 °C (lit.)
• SMILES string: C[Si](C)(C)O[Si](C)(C)C
• InChI: 1S/C6H18OSi2/c1-8(2,3)7-9(4,5)6/h1-6H3
• InChI key: UQEAIHBTYFGYIE-UHFFFAOYSA-N

Description

General description

HMDSO(hexamethyldisiloxane) is an organosilicon compound. It is a non-toxic, environmentally friendly monomer. It can be used as a precursor to synthesize organosilicon thin films. It serves as a silylating agent for carboxylic acids and alcohols. Additionally, it is used in the preparation of aroyl chlorides. HMDSO is commonly used as a water-repellent.

Application

Hexamethyldisiloxane is used:

• As a modifying agent in the presence of ethanol/n-hexane solution for the preparation of hydrophobic and hydrophilic sodium silicate-based silica xerogels.
• To form the dielectric layers in the MIM(metal-insulator-metal) structure that is consisting of graphene quantum dots(GQDs) to prepare two-terminal NVM (non-volatile-memory) devices.

Features and Benefits

Hexamethyldisiloxanehas high thermal stability.

Other Notes

Pour une silylation facile des acides carboxyliques; comme accepteur d′anions chloré dans la synthèse des esters sulfiniques

Informations sur la sécurité

• Pictogrammes: GHS02,GHS09
• Mot-clé: Danger
• Codes de danger: H225,H410
• Mentions de précaution: P210 - P233 - P240 - P241 - P242 - P273
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 2
• Classe de stockage: 3 - Flammable liquids
• Que se passe-t-il ?: WGK 2
• Point d'éclair (°F): 21.2 °F - closed cup
• Point d'éclair (°C): -6 °C - closed cup
• EPI (équipement de protection individuelle): Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter