426296

Bromure de tétraméthylammonium

ACS reagent grade, ≥98.0%, powder

• Synonyme(s) : N,N,N-trimethyl-methanaminium bromide, TMAB
• Formule linéaire : (CH₃)₄N(Br)
• Numéro CAS: 64-20-0
• Poids moléculaire : 154.05
• NACRES: NA.21
• PubChem Substance ID: 24866694
• UNSPSC Code: 12352100
• EC Number: 200-581-2
• MDL number: MFCD00011626
• Beilstein/REAXYS Number: 3620955
• Assay: ≥98.0%
• Grade: ACS reagent
• Form: powder

Propriétés

• Nom du produit: Bromure de tétraméthylammonium, ACS reagent, ≥98.0%
• grade: ACS reagent
• Quality Segment: 200
• assay: ≥98.0%
• form: powder
• reaction suitability: core: ammonium, reaction type: phase-transfer, reagent type: organic catalyst
• impurities: ≤0.5% trimethylamine hydrobromide, ≤0.5% trimethylamine
• mp: >300 °C (lit.)
• functional group: amine
• SMILES string: [Br-].C[N+](C)(C)C
• InChI: 1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
• InChI key: DDFYFBUWEBINLX-UHFFFAOYSA-M

Description

General description

Tetrabutylammonium bromide is a quaternary ammonium compound that is widely used as a phase transfer catalyst. Absolute viscosities of its aqueous solutions have been measured at various temperatures (20,25 and 30°C). Various physical properties (activity coefficient up to saturation, conductance, density and solubility in water) of TMABr have been evaluated.

Application

Tetrabutylammonium bromide (TBAB) may be used in the molten state in the following processes:

• Synthesis of (2S)-5-(3-phenyl-2-phthalimidylpropanoylamino)isophthalic acid.
• Synthesis of alkyl-substituted pyrroles in the absence of catalyst and organic solvent.
• Synthesis of dithioacetals from acetals by transthioacetalisation in a solvent free environment.
• Synthesis of polyamides (PAs) by the polymerization of terephthalic acid and diisocyanates.
• Catalyze the addition of thiols to conjugated alkenes.
• Dehydrochlorination of poly(vinyl chloride).

Informations sur la sécurité

• Pictogrammes: GHS06
• Mot-clé: Danger
• Codes de danger: H300
• Mentions de précaution: P301 + P330 + P331 + P310
• Hazard Classifications: Acute Tox. 2 Oral
• Classe de stockage: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Que se passe-t-il ?: WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• EPI (équipement de protection individuelle): Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges