8.22040

N,N-Dimethyl-p-toluidine

for synthesis

• Synonyme(s) : N,N-Dimethyl-p-toluidine, 4-Dimethylaminotoluene
• Formule linéaire : 4-(CH₃)C₆H₄N(CH₃)₂
• Numéro CAS: 99-97-8
• Poids moléculaire : 135.21
• UNSPSC Code: 12352116
• EC Index Number: 202-805-4
• NACRES: NA.22
• MDL number: MFCD00008316
• Assay: ≥98.0% (GC)
• Form: oil

Propriétés

• vapor pressure: 0.1 hPa ( 20 °C)
• Quality Segment: 200
• assay: ≥98.0% (GC)
• form: oil
• autoignition temp.: 425 °C
• potency: 1650 mg/kg LD₅₀, oral (Rat)
• bp: 215 °C/1013 hPa
• mp: -15 °C
• transition temp: flash point 76 °C
• density: 0.94 g/cm³ at 20 °C
• storage temp.: 2-30°C
• SMILES string: N(C)(C)c1ccc(cc1)C
• InChI: 1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3
• InChI key: GYVGXEWAOAAJEU-UHFFFAOYSA-N

Description

Application

• Zinc catalysed electrophilic C–H borylation of heteroarenes: This article explores a zinc-catalyzed process for borylation of heteroarenes using N,N-dimethyl-p-toluidine (Grundy et al., 2021).



• C–H bond sulfonylation of anilines with the insertion of sulfur dioxide under metal-free conditions: Details a sulfonylation reaction involving N,N-dimethyl-p-toluidine under metal-free conditions (Zhou et al., 2018).

Analysis Note

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.935 - 0.937
Identity (IR): passes test

Informations sur la sécurité

• pictograms: GHS06,GHS08
• signalword: Danger
• flash_point_f: 168.8 °F - closed cup
• flash_point_c: 76 °C - closed cup
• hcodes: H301 + H311,H317,H330,H350,H361f,H373,H412
• pcodes: P202 - P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P310
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 1B - Repr. 2 - Skin Sens. 1 - STOT RE 2
• target_organs: Respiratory Tract,Blood
• Classe de stockage: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials