8.04918

Potassium tert-butylate

for synthesis

• Synonyme(s) : Potassium tert-butylate
• Formule linéaire : (CH₃)₃COK
• Numéro CAS: 865-47-4
• Poids moléculaire : 112.21
• UNSPSC Code: 12352107
• EC Index Number: 212-740-3
• NACRES: NA.22
• MDL number: MFCD00012162
• Assay: ≥98.0% (acidimetric)
• Grade: synthesis grade
• Form: powder
• Solubility: water: soluble (Hydrolysis, (rigorous decomposition))

Propriétés

• Quality Segment: 200
• grade: synthesis grade
• vapor pressure: 0.02 hPa ( 20 °C)
• assay: ≥98.0% (acidimetric)
• form: powder
• autoignition temp.: 483 °C
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• pH: 13 (20 °C, 5 g/L in H₂O, Hydrolysis)
• mp: 256-258 °C
• solubility: water: soluble (Hydrolysis, (rigorous decomposition))
• density: 1.19 g/cm³ at 20 °C
• bulk density: 500 kg/m³
• greener alternative category: Aligned
• storage temp.: 2-30°C
• SMILES string: [K+].[O-]C(C)(C)C
• InChI: 1S/C4H9O.K/c1-4(2,3)5;/h1-3H3;/q-1;+1
• InChI key: LPNYRYFBWFDTMA-UHFFFAOYSA-N

Description

General description

Potassium tert-butylate (Potassium tert-Butoxide) is a strong, non-nucleophilic alkoxide base in organic chemistry. Potassium tert-butoxide catalyzes the reaction of hydro silanes and heterocyclic compounds to generate the silyl derivatives. It is used to catalyze the Michael addition reaction, Ramberg-Baecklund reaction, Pinacol rearrangement.

Application

Potassium tert-butylate is used to catalyzes the Michael addition reaction.

Features and Benefits

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign and has been enhanced for catalytic efficiency. Click here for more information.

Analysis Note

Assay (acidimetric): ≥ 98,0 %(m)
Free KOH: ≤ 1 %(m)
Identity (IR): conforms

Informations sur la sécurité

• Pictogrammes: GHS02,GHS05
• Mot-clé: Danger
• supp_hazards: EUH014
• Classe de stockage: 4.2 - Pyrophoric and self-heating hazardous materials
• Que se passe-t-il ?: WGK 1
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Codes de danger: H228,H252,H314
• Mentions de précaution: P210 - P235 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 2 - Skin Corr. 1A