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8.04604

Sigma-Aldrich

Hydrazin hydrate solution

80% solution in water, for synthesis

Synonyme(s) :

Hydrazine hydrate

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About This Item

Code UNSPSC :
12352402
Nomenclature NACRES :
NA.22
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Nom du produit

Hydrazin hydrate (80% solution in water), for synthesis

Pression de vapeur

13 hPa ( 20 °C)

Niveau de qualité

Forme

solution

Température d'inflammation spontanée

310 °C

Limite d'explosivité

4.7-99 % (v/v) refers to pure substance()

Pertinence de la réaction

reagent type: reductant

pH

10.6-10.7 (20 °C, 10 g/L in H2O)

pb

117-119 °C/1013 hPa

Pf

-60 °C

Densité

1.02 g/cm3 at 20 °C

Température de stockage

15-25°C

Application

Hydrazin hydrate (80% solution in water) can be used as a reducing agent for the reduction of exfoliated graphene oxide (GO), which is used for the preparation of GO nanocomposites.[1] It is also used as a reagent in the synthesis of 3-amino-2-thiohydantoins by reacting with alkyl isothiocynatocarboxylates.[2]

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Code de la classe de stockage

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

195.8 °F - closed cup - DIN 51758

Point d'éclair (°C)

91 °C - closed cup - DIN 51758


Certificats d'analyse (COA)

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Synthetical Application of Alkyl 2-isothiocyanatocarboxylates. A Simple Synthesis of 5-Substituted-3-amino-2-thioxo-4-imidazolidinones (3-Amino-2-thiohydantoins)
Floch L, et al.
Molecules (Basel), 4(10), 279-286 (1999)

Articles

Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.

Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.

Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.

Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.

Questions

  1. It is 80% of hydrazine hydroxide in water (about 52% of hydrazine in water) or 80% of hydrazine in water. There is no MW on page. I thought that is less than 1 molecule of water to 1 molecule of hydrazine (sth like hydrazine half-hydrate).

    1 answer
    1. It is the former. Product 8.04604 is approximately 80 percent hydrazine hydrate by weight, which corresponds to 51.2 percent hydrazine by weight. Based on a density of 1.02 g/mL for this solution, which is 51.2 percent hydrazine, and a molecular weight of 32.05 for hydrazine (N2H4), the molarity of this solution is approximately 16 M.

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