If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
1.03792
Ammonium iron(II) sulfate hexahydrate
for analysis EMSURE® ISO
Synonyme(s) :
Ammonium iron(II) sulfate hexahydrate
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A propos de cet article
agency
reag. ISO
Quality Segment
product line
EMSURE®
assay
99.0-101.5% (manganometric)
form
solid
potency
3250 mg/kg LD50, oral (Rat)
pH
3.0-5.0 (25 °C, 5% in water)
mp
39-41 °C (decomposition)
solubility
269 g/L
density
1.86 g/cm3 at 20 °C
bulk density
900 kg/m3
anion traces
chloride (Cl-): ≤0.001%, phosphate (PO43-): ≤0.002%
cation traces
Ca: ≤0.002%, Cu: ≤0.002%, Fe3+: ≤0.02%, K: ≤0.01%, Mg: ≤0.01%, Mn: ≤0.05%, Na: ≤0.01%, Pb: ≤0.001%, Zn: ≤0.003%
storage temp.
15-25°C
SMILES string
[Fe+3].[S](=O)(=O)([O-])[O-].[S](=O)(=O)([O-])[O-].[N+H4].[N+H4].O.O.O.O.O.O
InChI
1S/Fe.2H3N.2H2O4S.6H2O/c;;;2*1-5(2,3)4;;;;;;/h;2*1H3;2*(H2,1,2,3,4);6*1H2/q+3;;;;;;;;;;/p-2
InChI key
SHHFGSWBFZVUNE-UHFFFAOYSA-L
Application
- Water-Mediated Green and Efficient Synthesis of Bis(Indolyl)methanes Using Ammonium Iron(II) Sulfate.: This research highlights the use of ammonium iron(II) sulfate hexahydrate in the green synthesis of bis(indolyl)methanes. The study demonstrates the compound′s efficiency and eco-friendliness in catalyzing reactions in water, offering a sustainable alternative in organic synthesis (Letters in Organic Chemistry, 2020).
- Determination of Ferromanganese and Ferrosilicon by Ammonium Ferrous Sulfate Titration and ICP.: This paper discusses the analytical methods for determining ferromanganese and ferrosilicon using ammonium iron(II) sulfate titration and inductively coupled plasma (ICP). The study underscores the compound′s role in precise quantitative analysis in metallurgical processes (Modern Analytical Chemistry Research, 2020).
Analysis Note
pH-value (5%; water; 25°C) 3.0 - 5.0
Chloride (Cl): ≤ 0.001 %
Phosphate (PO₄): ≤ 0.002 %
Iron(III)-salts (Fe³⁺): ≤ 0.02 %
Ca (Calcium): ≤ 0.002 %
Cu (Copper): ≤ 0.002 %
K (Potassium): ≤ 0.01 %
Mg (Magnesium): ≤ 0.01 %
Mn (Manganese): ≤ 0.05 %
Na (Sodium): ≤ 0.01 %
Pb (Lead): ≤ 0.001 %
Zn (Zinc): ≤ 0.003 %
Corresponds to ISO
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Classe de stockage
11 - Combustible Solids
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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