683094

HS157

97%, Umicore, powder

• Synonyme(s) : Bis(1,5-cyclooctadiene)diiridium(I) dichloride, [Ir(1,5-cod)Cl]2, 1,5-Cyclooctadiene-iridium(I) chloride dimer, Chloro(1,5-cyclooctadiene)iridium(I) dimer, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Iridium(I) chloride 1,5-cyclooctadiene complex dimer, [Ir(1,5-cod)Cl]₂, [Ir(cod)Cl]2
• Formule empirique (notation de Hill) : C₁₆H₂₄Cl₂Ir₂
• Numéro CAS: 12112-67-3
• Poids moléculaire : 671.70
• NACRES: NA.22
• PubChem Substance ID: 329760792
• UNSPSC Code: 12161600
• EC Number: 235-170-7
• MDL number: MFCD00012414

Propriétés

• Nom du produit: HS157, Umicore, 97%
• Quality Segment: 200
• assay: 97%
• form: powder
• reaction suitability: core: iridium, reaction type: C-H Activation, reagent type: catalyst
• mp: 205 °C (dec.) (lit.)
• SMILES string: Cl[Ir].Cl[Ir].C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
• InChI key: ZFOUDQNHNLDNLD-MIXQCLKLSA-L

Description

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Metal precursor for asymmetric allylic substitutions.

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Informations sur la sécurité

• Classe de stockage: 11 - Combustible Solids
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves
• pictograms: GHS07
• signalword: Warning
• hcodes: H302
• pcodes: P264 - P270 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral