677264

APhos

95%, solid

• Synonyme(s) : (4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine, A-^taPhos, [4-(Dimethylamino)phenyl]bis(tert-butyl)phosphine
• Formule empirique (notation de Hill) : C₁₆H₂₈NP
• Numéro CAS: 932710-63-9
• Poids moléculaire : 265.37
• UNSPSC Code: 12352116
• PubChem Substance ID: 24885360
• NACRES: NA.22
• MDL number: MFCD09265102

Propriétés

• Nom du produit: APhos, 95%
• Quality Segment: 100
• assay: 95%
• form: solid
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand; reaction type: Cross Couplings
• sustainability: Sustainability features
• mp: 57-61 °C
• functional group: phosphine
• SMILES string: CN(C)c1ccc(cc1)P(C(C)(C)C)C(C)(C)C
• InChI: 1S/C16H28NP/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8/h9-12H,1-8H3
• InChI key: IQTHEAQKKVAXGV-UHFFFAOYSA-N

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is the APHOS ligand system for asymmetric catalysis, providing high enantioselectivity in various metal-catalyzed transformations. Click here for more information.

Application

Ligand used to prepare a palladium dichloride catalyst (678740) on treatment with PdCl₂(COD). The catalyst effectively cross-couples aryl boronic acids with heteroaryl chlorides.

Informations sur la sécurité

• Pictogrammes: GHS05
• Mot-clé: Danger
• Codes de danger: H314
• Mentions de précaution: P280 - P305 + P351 + P338 - P310
• Hazard Classifications: Skin Corr. 1B
• Classe de stockage: 8B - Non-combustible, corrosive hazardous materials
• Que se passe-t-il ?: WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable