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449229

Sigma-Aldrich

Iridium

evaporation slug, diam. × L 0.6 cm × 1.2 cm, 99.9% trace metals basis

Synonyme(s) :

Iridium black

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About This Item

Formule empirique (notation de Hill):
Ir
Numéro CAS:
7439-88-5
Poids moléculaire :
192.22
Numéro MDL:
MFCD00011062
Code UNSPSC :
12141720
ID de substance PubChem :
24868465
Nomenclature NACRES :
NA.23

Pureté

99.9% trace metals basis

Forme

evaporation slug

Résistivité

4.71 μΩ-cm

Diam. × L

0.6 cm × 1.2 cm

Poids

~7.6 g (one slug)

Point d'ébullition

4130 °C (lit.)

Pf

2450 °C (lit.)

Densité

22.65 g/cm3 (lit.)

Chaîne SMILES 

[Ir]

InChI

1S/Ir

Clé InChI

GKOZUEZYRPOHIO-UHFFFAOYSA-N

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Application

  • Single Atom Iridium Decorated Nickel Alloys Supported on Segregated MoO(2) for Alkaline Water Electrolysis.: The study presents an innovative approach to enhance alkaline water electrolysis using single-atom iridium catalysts, resulting in improved efficiency and stability of the process (Wang et al., 2024).
  • An Aqueous Redox Flow Battery Using CO(2) as an Active Material with a Homogeneous Ir Catalyst.: This paper explores the use of iridium catalysts in an aqueous redox flow battery, utilizing CO2 as an active material to improve energy storage capabilities (Kanega et al., 2023).
  • Kinetic Acceleration of Lithium Polysulfide Conversion via a Copper-Iridium Alloying Catalytic Strategy in Li-S Batteries.: This research highlights the use of copper-iridium alloys to accelerate the conversion of lithium polysulfides, significantly enhancing the performance of lithium-sulfur batteries (Zhai et al., 2022).
  • Introducing High-Valence Iridium Single Atoms into Bimetal Phosphides toward High-Efficiency Oxygen Evolution and Overall Water Splitting.: The study demonstrates the integration of high-valence iridium single atoms into bimetal phosphides, leading to highly efficient oxygen evolution and water splitting processes (Yang et al., 2023).

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

nwg

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Certificats d'analyse (COA)

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José Luis Núñez-Rico et al.
Organic letters, 15(8), 2066-2069 (2013-04-12)
Iridium(I) complexes of enantiomerically pure phosphine-phosphite ligands ([Ir(Cl)(cod)(P-OP)]) efficiently catalyze the enantioselective hydrogenation of diverse C═N-containing heterocyclic compounds (benzoxazines, benzoxazinones, benzothiazinones, and quinoxalinones; 25 examples, up to 99% ee). A substrate-to-catalyst ratio as high as 2000:1 was reached.
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played
Rui Cao et al.
Journal of medicinal chemistry, 56(9), 3636-3644 (2013-04-19)
The cellular behavior and toxicity effect of organometallic complexes depend largely on their peripheral ligands. In this study, we have synthesized a series of novel luminescent cationic iridium(III) complexes by tuning the ancillary N(∧)N ligand based on a structure [Ir(ppy)2(N(∧)N)](+)
M Y Zhang et al.
Optics express, 21 Suppl 1, A173-A178 (2013-02-15)
We have investigated the transport characteristics of red phosphorescent dye bis(1-(phenyl)isoquinoline) iridium (III) acetylanetonate (Ir(piq)₂acac) doped 4,4',4"-tri(N-carbazolyl)triphenylamine (TCTA), and found that the increasing doping ratio was facilitated to improve the ability of hole transporting. A high color rendering index (CRI)
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