445274

Imino-tris(dimethylamino)phosphorane

97%

• Synonyme(s) : N,N,N′,N′,N″,N″-Hexamethylphosphorimidic triamide, Phosphazene base P₁-H
• Formule linéaire : [(CH₃)₂N]₃P=NH
• Numéro CAS: 49778-01-0
• Poids moléculaire : 178.22
• UNSPSC Code: 12161700
• NACRES: NA.22
• PubChem Substance ID: 24868170
• MDL number: MFCD00216725
• Beilstein/REAXYS Number: 1933051
• Assay: 97%
• Form: liquid

Propriétés

• Quality Segment: 200
• assay: 97%
• form: liquid
• refractive index: n20/D 1.476 (lit.)
• density: 0.979 g/mL at 25 °C (lit.)
• functional group: amine
• SMILES string: CN(C)P(=N)(N(C)C)N(C)C
• InChI: 1S/C6H19N4P/c1-8(2)11(7,9(3)4)10(5)6/h7H,1-6H3
• InChI key: GKTNLYAAZKKMTQ-UHFFFAOYSA-N

Description

Application

Imino-tris(dimethylamino)phosphorane is a base that can be used:

• As a reagent in the deboronation of ortho and meta carboranes.
• As an organocatalyst in the synthesis of cyclic organic carbonates using glycerol under solvent-free conditions.

Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen–Bases

Informations sur la sécurité

• Pictogrammes: GHS05
• Mot-clé: Danger
• Codes de danger: H314
• Mentions de précaution: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Classe de stockage: 8A - Combustible corrosive hazardous materials
• Que se passe-t-il ?: WGK 3
• Point d'éclair (°F): 235.4 °F - closed cup
• Point d'éclair (°C): 113 °C - closed cup
• EPI (équipement de protection individuelle): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter