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235083

Sodium bis(trimethylsilyl)amide

95%

Synonyme(s) :

Hexamethyldisilazane sodium salt

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A propos de cet article

Formule linéaire :
[(CH3)3Si]2NNa
Numéro CAS:
Poids moléculaire :
183.37
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-983-8
Beilstein/REAXYS Number:
3629917
MDL number:
eCl@ss:
32150917
Assay:
95%
Form:
powder or chunks
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Quality Segment

assay

95%

form

powder or chunks

bp

202 °C/at 1-3  hPa

mp

171-175 °C (lit.), 175-171 °C (lit.)

SMILES string

C[Si](C)(C)N([Na])[Si](C)(C)C

InChI

1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1

InChI key

WRIKHQLVHPKCJU-UHFFFAOYSA-N

Application

Useful for the generation of carbenes, the amination of sulfenamides, and the preparation of lanthanide complexes.

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Cet article
36805980631245585
description

95%

description

0.6 M in toluene

description

40% in THF

description

1.0 M in THF

assay

95%

assay

-

assay

-

assay

-

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

200

form

powder or chunks

form

liquid

form

liquid

form

liquid

bp

202 °C/at 1-3  hPa

bp

-

bp

-

bp

-

mp

175-171 °C (lit.), 171-175 °C (lit.)

mp

-

mp

-

mp

-

Hexamethyldisilazane sodium salt

-

CAS 1070-89-9 sodium bis(trimethylsilyl)amide, sodium bis(trimethylsilyl)amide reagent for enolization, sodium bis(trimethylsilyl)amide solution, NaHMDS solution for synthesis, ACS grade sodium bis(trimethylsilyl)amide, sodium bis(trimethylsilyl)amide in quantities, HMN-Na Sol for carbonyl enolization, Hexamethyldisilazane sodium salt solution, sodium bis(trimethylsilyl)amide for primary amine synthesis, sodium bis(trimethylsilyl)amide reagent for Wittig reaction, NaHMDS solution for aminomethylation, NaHMDS solution for laboratory applications, high purity sodium bis(trimethylsilyl)amide

-


Pictogrammes

Corrosion

Mot-clé

Danger

Codes de danger

Hazard Classifications

Skin Corr. 1B

supp_hazards

Classe de stockage

8A - Combustible corrosive hazardous materials

Que se passe-t-il ?

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

EPI (équipement de protection individuelle)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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