212911

Palladium hydroxide on carbon

extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support, solid

• Synonyme(s) : Pd(OH)₂/C, Pearlman’s catalyst
• Formule empirique (notation de Hill) : H₂O₂Pd
• Numéro CAS: 12135-22-7
• Poids moléculaire : 140.43
• NACRES: NA.22
• PubChem Substance ID: 24852754
• UNSPSC Code: 12161600
• EC Number: 235-219-2
• MDL number: MFCD00064599

Propriétés

• Nom du produit: Palladium hydroxide on carbon, extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support
• form: powder
• Quality Segment: 200
• contains: ≤50% water
• reaction suitability: core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: inorganic catalyst
• extent of labeling: 20 wt. % loading (dry basis)
• matrix: carbon, wet support
• SMILES string: O[Pd]O
• InChI: 1S/2H2O.Pd/h2*1H2;/q;;+2/p-2
• InChI key: NXJCBFBQEVOTOW-UHFFFAOYSA-L

Description

Application

Effectively catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes.

Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proven successful even where other palladium-on-carbon catalysts have failed.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Addition of Pd/C to Pd(OH)₂/C improves the efficiency of N- or O-debenzylation.

Informations sur la sécurité

• Classe de stockage: 11 - Combustible Solids
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• EPI (équipement de protection individuelle): Eyeshields, Gloves, type N95 (US)