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178985

Borane trimethylamine complex

97%

Synonyme(s) :

NSC 10220, NSC 145941, NSC 53323, Trihydro(trimethylamine)boron, Trimethylamine borane

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A propos de cet article

Formule linéaire :
(CH3)3N · BH3
Numéro CAS:
Poids moléculaire :
72.95
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-850-4
Beilstein/REAXYS Number:
3905060
MDL number:
Assay:
97%
Form:
solid
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Quality Segment

assay

97%

form

solid

reaction suitability

reagent type: reductant

bp

172 °C (lit.)

mp

92-94 °C (lit.)

functional group

amine

SMILES string

[BH3-][N+](C)(C)C

InChI

1S/C3H12BN/c1-5(2,3)4/h1-4H3

InChI key

KQVSXUGMDCAISO-UHFFFAOYSA-N

Application

Stable, easy-to-handle source of borane for the reduction of ketones and Schiff bases and for the hydroboration of olefins.
Reducing agent for the preparation of plate-type palladium-zinc oxide catalyst

Reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents

Catalyst for:
  • Regioselective reductive opening of benzylidene acetal glycosides
  • Polarity reversal

Used to study
  • Electrodeposition condition effects on magnetism of cobalt-iron magnetic films
  • Boron-nitrogen bond dissociation energies and physiological activities of boronated compounds

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Cet article
180203179752180238
description

97%

description

95%

description

~8 M BH3

description

97%

assay

97%

assay

95%

assay

-

assay

97%

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

200

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

reaction suitability

reagent type: reductant

form

solid

form

-

form

liquid

form

solid

bp

172 °C (lit.)

bp

-

bp

-

bp

-

mp

92-94 °C (lit.)

mp

97-99 °C (lit.)

mp

10-11 °C (lit.)

mp

36 °C (lit.)


Pictogrammes

FlameExclamation mark

Mot-clé

Danger

Codes de danger

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Classe de stockage

4.1B - Flammable solid hazardous materials

Que se passe-t-il ?

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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