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D7766

Sigma-Aldrich

1,5-Diphenylcarbazide

reagent grade

Synonym(s):

1,5-Diphenylcarbohydrazide, sym.-Diphenylcarbazide

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About This Item

Linear Formula:
C6H5NHNHCONHNHC6H5
CAS Number:
Molecular Weight:
242.28
Beilstein:
752039
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

grade

reagent grade

Quality Level

Assay

≥99% (TLC)

form

powder

mp

170-175 °C (lit.)

functional group

amine
hydrazide

storage temp.

2-8°C

SMILES string

O=C(NNc1ccccc1)NNc2ccccc2

InChI

1S/C13H14N4O/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14-15H,(H2,16,17,18)

InChI key

KSPIHGBHKVISFI-UHFFFAOYSA-N

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General description

1,5-Diphenylcarbazide (DPC) is a colorimetric reagent commonly employed in the determination of trace metals.

Application

1,5-Diphenylcarbazide may be used in the following processes:
  • Quantification of palladium and platinum by spectrophotometry.
  • As a mediator for the functionalization of carbon paste electrodes employed in the estimation of Hg(II) ions by differential pulse voltammetry.
  • Alteration of gold nanoparticles (AuNPs), employed for the detection of chromium (VI) ions via colorimetry.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Spectrophotometric determination of platinum and palladium with 1, 5-diphenylcarbazide.
Brajter K, et al.
Fresenius Journal of Analytical Chemistry, 328(7), 598-598 (1987)
Photometric and visual detection of Cr (VI) using gold nanoparticles modified with 1, 5-diphenylcarbazide.
Liu, L, et al.
Microchimica Acta, 1-7 (2016)
Hg (II) voltammetry on a 1, 5-diphenylcarbazide containing carbon paste electrode.
Navratilova Z.
Electroanalysis, 3(8), 799-802 (1991)
Kinetic method for the determination of trace amounts of copper (II) in water matrices by its catalytic effect on the oxidation of 1, 5-diphenylcarbazide.
Crespo GA, et al.
Analytica Chimica Acta, 539(1), 317-325 (2005)
W Hillier et al.
Biochemistry, 36(1), 76-85 (1997-01-07)
The behavior of photosystem II (PSII) reactions was investigated under conditions of decreasing water content by the addition of increasing concentrations of ethylene glycol (EG). The photosynthetic activities were measured for PSII samples either directly in aqueous solutions of EG

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