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87208

Supelco

Myristyltrimethylammonium bromide

suitable for ion pair chromatography, LiChropur™, ≥99.0% (AT)

Synonym(s):

Tetradecyltrimethylammonium bromide, Trimethyl(tetradecyl)ammonium bromide

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About This Item

Linear Formula:
CH3(CH2)13N(Br)(CH3)3
CAS Number:
1119-97-7
Molecular Weight:
336.39
Beilstein:
3633227
EC Number:
214-291-9
MDL number:
MFCD00011770
UNSPSC Code:
12000000
PubChem Substance ID:
329769512
NACRES:
NB.21

description

cationic

Quality Level

100

Assay

≥99.0% (AT)

form

crystals

quality

LiChropur™

mol wt

micellar avg mol wt 27,000

aggregation number

80

technique(s)

ion pair chromatography: suitable

CMC

4-5 mM (20-25°C)

mp

245-250 °C (lit.)

λ

10 % in H2O

UV absorption

λ: 240 nm Amax: ≤0.08
λ: 250 nm Amax: ≤0.05
λ: 260 nm Amax: ≤0.04
λ: 500 nm Amax: ≤0.02

suitability

corresponds to standard for filter test

SMILES string

[Br-].CCCCCCCCCCCCCC[N+](C)(C)C

InChI

1S/C17H38N.BrH/c1-5-6-7-8-9-10-11-12-13-14-15-16-17-18(2,3)4;/h5-17H2,1-4H3;1H/q+1;/p-1

InChI key

CXRFDZFCGOPDTD-UHFFFAOYSA-M

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General description

Ion-pairing reagents as mobile phase additives facilitate the separation of ionic and highly polar substances on reversed phase HPLC columns. Their purity is an important parameter for their successful application. Sigma-Aldrich offers an wide range of tailor-made reagents for anionic (quaternary ammonium and phosphonium salts) and cationic (alkanesulfonates) analyzes. All mobile phase additives are subject to rigorous testing with special emphasis on the requirements of modern reversed phase HPLC:

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Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - STOT RE 2 Oral - STOT SE 3

Target Organs

Gastrointestinal tract, Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL1954
BCCD0749
BCBS7537V
BCBJ3648V
BCBB7480V

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Dulan B Gunasekara et al.
Electrophoresis, 32(8), 832-837 (2011-03-26)
The combination of microchip electrophoresis with amperometric detection leads to a number of analytical challenges that are associated with isolating the detector from the high voltages used for the separation. While methods such as end-channel alignment and the use of
Yan Jiang et al.
The journal of physical chemistry. B, 113(24), 8357-8361 (2009-05-26)
Three kinds of conventional surfactants, namely, two nonionic surfactants [polyethylene glycol (23) lauryl ether (Brij-35) and Triton X-100 (TX-100)], one cationic surfactant [n-tetradecyltrimethyl ammonium bromide (TTAB)], and an anionic surfactant [sodium n-dodecyl sulfate (SDS)}, were mixed into the quaternary ammonium
Yuri Borodko et al.
Langmuir : the ACS journal of surfaces and colloids, 25(12), 6665-6671 (2009-04-29)
The vibrational spectra of platinum nanoparticles (12 nm) capped with tetradecyltrimethylammonium bromide, C(14)TAB, were investigated by Fourier transform infrared (FTIR) spectroscopy. We have shown that the thermal decay of Pt-C(14)TAB nanoparticles in N(2), H(2), and O(2) atmospheres leads to the
Hayat M Marafie et al.
Talanta, 91, 26-32 (2012-03-01)
Two conventional plastic membrane electrodes that are selective for the tetradecyltrimethylammonium cation (TTA) have been prepared. The ion exchangers of these sensors were the ion associate, TTA-PT, and the ion aggregate, TTA-PSS, where PT and PSS are phosphotungstate and polystyrene
Aline Delbos et al.
Physical review. E, Statistical, nonlinear, and soft matter physics, 84(1 Pt 1), 011404-011404 (2011-08-27)
We investigate experimentally the behavior of liquid foams pumped at a given flow rate through a single pore, in the situation where the pore diameter is smaller than the bubble diameter. Results reveal that foam invasion can be observed only
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