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60360

Sigma-Aldrich

Potassium phthalate monobasic

puriss. p.a., ≥99.5% (T)

Synonym(s):

KHP, Phthalic acid monopotassium salt, Potassium biphthalate, Potassium hydrogen phthalate

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About This Item

Linear Formula:
HOOCC6H4COOK
CAS Number:
Molecular Weight:
204.22
Beilstein:
3637128
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

puriss. p.a.

Quality Level

Assay

≥99.5% (T)

form

solid

pH

4

mp

295-300 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤20 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤100 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

functional group

carboxylic acid

SMILES string

[K+].OC(=O)c1ccccc1C([O-])=O

InChI

1S/C8H6O4.K/c9-7(10)5-3-1-2-4-6(5)8(11)12;/h1-4H,(H,9,10)(H,11,12);/q;+1/p-1

InChI key

IWZKICVEHNUQTL-UHFFFAOYSA-M

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General description

Potassium phthalate monobasic (KHP) is the monopotassium salt of pthalic acid. It has been proposed as a certified reference material (CRM) under ISO/IEC 17025 and ISO Guide 34 accreditation. Its spectral shift, multiplicity, solubility and relaxation times in different solvents have been reported.

Application

Potassium phthalate monobasic may be used as a primary standard in acidimetric titration and also to prepare potassium phthalate buffer solution for pH calibration.

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

387.1 °F - Pensky-Martens closed cup

Flash Point(C)

197.3 °C - Pensky-Martens closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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2, 4, 6-Trinitrobenzoic acid as a primary standerd in acidimetry.
Smith GF and Wilkins DH.
Analytica Chimica Acta, 8, 209-216 (1953)
Determination of standard pH values for potassium hydrogen phthalate reference buffer solutions in 10, 20, 50, 64 and 84.2 wt per cent methanol/water mixed solvents at temperatures from 283.15 to 313.15 K.
Mussini T, et al.
Electrochimica Acta, 28(11), 1593-1598 (1983)
J M Padró et al.
Talanta, 107, 95-102 (2013-04-20)
Dispersive ionic liquid-liquid microextraction combined with liquid chromatography and UV detection was used for the determination of two antichagasic drugs in human plasma: nifurtimox and benznidazole. The effects of experimental parameters on extraction efficiency-the type and volume of ionic liquid
H Fromme et al.
Environment international, 61, 64-72 (2013-10-10)
Phthalates have been used for decades in large quantities, leading to the ubiquitous exposure of the population. In an investigation of 63 German daycare centers, indoor air and dust samples were analyzed for the presence of 10 phthalate diesters. Moreover
Tye E Arbuckle et al.
Environment international, 68, 55-65 (2014-04-09)
Bisphenol A (BPA) and phthalates are endocrine disruptors possibly linked to adverse reproductive and neurodevelopmental outcomes. These chemicals have commonly been measured in urine in population surveys; however, such data are limited for large populations of pregnant women, especially for

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