Journal of the American Chemical Society, 134(30), 12604-12610 (2012-07-10)
A general mechanism for the oxygen-assisted synthesis of amides over metallic gold and silver surfaces has been derived from the study of acetaldehyde and dimethylamine in combination with previous work, allowing detailed comparison of the two surfaces' reactivities. Facile acetylation
N-Nitrosodimethylamine (NDMA) formation experiments conducted in phosphate buffer demonstrated that in waters containing monochloramine, the presence of bromide ion enhanced NDMA formation at the relatively high pH values of 8 and 9 after 24 h of reaction time, which was
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 83(1), 88-93 (2011-09-17)
The effect of different solvents on the fluorescent properties of 2-(dimethylamine)fluorene (DAF) were studied. In aprotic solvents we detected a strongly emissive intramolecular charge transfer (ICT) state that decayed by intersystem crossing to triplet. In proton-accepting solvents DAF exhibits in
Therapeutic agents containing phosphate groups in their molecules have increasing therapeutic impact. The object of this study was to characterize the cationic polyelectrolyte Eudragit E100 (EuE100) as a carrier for drugs containing phosphate groups, using dexamethasone phosphate (DP) as a
Journal of hazardous materials, 229-230, 340-345 (2012-07-10)
The paper concerns formation of N-nitrosodimethylamine (NDMA) upon ozonation of dimethylamine (DMA) aqueous solutions. According to current hypothesis ozonated DMA is oxidized to N-dimethylhydroxylamine (DMHA), then to N-methylhydroxylamine (MHA) and finally to hydroxylamine (HA). HA subsequently reacts with the remain
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