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Supelco

Tolylfluanid

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C10H13Cl2FN2O2S2
CAS Number:
731-27-1
Molecular Weight:
347.26
Colour Index Number:
45430
Beilstein:
2949607
EC Number:
211-986-9
MDL number:
MFCD00055477
UNSPSC Code:
41116107
PubChem Substance ID:
329753720
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)c1ccc(C)cc1

InChI

1S/C10H13Cl2FN2O2S2/c1-8-4-6-9(7-5-8)15(18-10(11,12)13)19(16,17)14(2)3/h4-7H,1-3H3

InChI key

HYVWIQDYBVKITD-UHFFFAOYSA-N

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General description

Tolylfluanid is a phenylsulfamide fungicide, generally used in fertilizers. It can also be used as an antifouling agent in vessel paints.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Tolylfluanid may be used as a reference standard for the determination of the analyte in nutraceutical formulations using dispersive liquid-liquid microextraction(DLLME) coupled with gas chromatography-mass spectrometry method.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ3200
BCCB7968
BCBZ7089
BCBT9907
SZBD038XV

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Sigma-Aldrich

H3274

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Dispersive liquid-liquid microextraction followed by gas chromatography- mass spectrometry for the determination of pesticide residues in nutraceutical drops.
Szarka A, et al.
Journal of Chromatography A, 1570(1), 126- 134 (2018)
Aurélie Berthet et al.
Toxicology letters, 324, 38-45 (2020-02-18)
Tolylfluanid (TF) is a sensitizing biocide used in antifouling products and wood preservatives. Paint application is associated with skin exposure; however, the importance of this exposure route is uncertain as TF skin permeation rates are lacking in the peer-reviewed scientific
Robert M Sargis et al.
Biochimica et biophysica acta, 1822(6), 952-960 (2012-03-06)
Emerging data suggest that environmental endocrine disrupting chemicals may contribute to the pathophysiology of obesity and diabetes. In a prior work, the phenylsulfamide fungicide tolylfluanid (TF) was shown to augment adipocyte differentiation, yet its effects on mature adipocyte metabolism remain
S Gielen et al.
Communications in agricultural and applied biological sciences, 71(2 Pt A), 79-82 (2007-03-30)
The use of Euparen Multi (tolylfluanid) for controlling Botrytis cinerea in tomatoes has been decreased the last decade for several reasons. Because of the lack of different fungicides with a good efficacy it is important that growers can use different
H B Christensen et al.
Food additives and contaminants, 20(8), 728-741 (2003-09-18)
An HPLC-MS/MS method for the analysis of three pesticides in strawberries was developed and validated. Recoveries were measured at three spiking levels and ranged from 85 to 99% (mean recoveries). The effects of processing of strawberries ranging from rinsing to
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