Skip to Content
Merck

M1601

Sigma-Aldrich

Malonyl chloride

97%

Synonym(s):

Malonyl dichloride

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
CH2(COCl)2
CAS Number:
Molecular Weight:
140.95
Beilstein:
774044
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Pricing and availability is not currently available.

Quality Level

Assay

97%

refractive index

n20/D 1.465 (lit.)

bp

53-55 °C/19 mmHg (lit.)

density

1.449 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

ClC(=O)CC(Cl)=O

InChI

1S/C3H2Cl2O2/c4-2(6)1-3(5)7/h1H2

InChI key

SXYFKXOFMCIXQW-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
G1377PHR2733PHR2485
form

solid

form

powder

form

powder

form

solid

application(s)

pharmaceutical small molecule

application(s)

peptide synthesis

application(s)

pharmaceutical small molecule

application(s)

pharmaceutical small molecule

agency

traceable to USP 1686386

agency

-

agency

traceable to USP 1199308

agency

traceable to USP 1012517

API family

triglycine

API family

-

API family

diglycine

API family

glutamine

CofA

current certificate can be downloaded

CofA

-

CofA

-

CofA

current certificate can be downloaded

Application

Malonyl chloride can be used as a reactant for the synthesis of:
  • Alkaloids with tetracyclic cores such as cyclopiamide A and speradine E.[1]
  • 6-tetrathiafulvalene(TTF)-polymer by condensation polymerization with TTF-based dihydroxy monomer.[2]
  • N-doped TiO2 films by molecular layer deposition.[3]
  • Alkyne-substituted 1,3-oxazines by reaction with arylpropynamides.[4]

It can also be used as a coupling agent in the synthesis of block copolymers by anionic polymerization.[5]

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

116.6 °F - closed cup

Flash Point(C)

47 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis and Characterization of a Tetrathiafulvalene-Based Polymer
Lee SH, et al.
Bull. Korean Chem. Soc., 33(5), 1451-1456 (2012)
Nanoporous Nitrogen-Doped Titanium Dioxide with Excellent Photocatalytic Activity under Visible Light Irradiation Produced by Molecular Layer Deposition
Chen C, et al.
Angewandte Chemie (International Edition in English), 125(35), 9366-9370 (2013)
Total synthesis of cyclopiamide A and speradine E
Nakhla MC, et al.
Tetrahedron, 74(38), 5085-5088 (2018)
Mechanistic Pathway for the Formation of Radial Polystyrenes Using Diacyl Chloride
Kumar S, et al.
Macromolecules, 45(6), 2675-2681 (2012)
Preparation of Arylpropynamides and Their Reaction with Malonyl Acid Derivatives
Petina OA, et al.
Synthesis, 45(06), 803-809 (2013)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service