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95420

Sigma-Aldrich

Tungstic acid

≥98.0% (calcined substance, T), powder

Synonym(s):

Tungstic(VI) acid

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About This Item

Linear Formula:
H2WO4
CAS Number:
Molecular Weight:
249.85
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

≥98.0% (calcined substance, T)

form

powder

impurities

≤0.2% insoluble matter in NaOH

loss

≤9.0% loss on ignition

density

5.5 g/mL at 25 °C (lit.)

SMILES string

O[W](O)(=O)=O

InChI

1S/2H2O.2O.W/h2*1H2;;;/q;;;;+2/p-2

InChI key

CMPGARWFYBADJI-UHFFFAOYSA-L

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General description

Tungstic acid may be prepared by either digesting tungstate of lime or by treating tungsten with hydrochloric acid. 1

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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The journal of physical chemistry. A, 111(11), 2166-2171 (2007-03-29)
The catalytic system formed by tungstic acid and its complexes with H2O2 and phenylphosphonic acid has been analyzed from the experimental and theoretical points of view. Previous structural studies by XRD proved the validity of the DFT proposed models and
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Thierry Barré et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(4), 551-557 (2005-01-15)
This study is focused on the composition and the evolution of tungstate ions solutions as a function of pH and increasing concentrations. The Raman analysis showed that, during the titration of the tungstate solutions, WO4(2-), HWO4- ions and probably W2O7(2-)
Shaopu Liu et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 19(7), 1055-1060 (2003-07-26)
In a weak acid medium, when an isopoly-tungstic acid reacts with berberine to form an ion-association complex, strong resonance Rayleigh scattering (RRS) appears and obvious frequency-doubling scattering (FDS) as well as second-order scattering (SOS) come into being. The scattering peaks
J W White et al.
Journal - Association of Official Analytical Chemists, 72(6), 907-911 (1989-11-01)
Using the difference in stable carbon isotope ratio between a honey and its protein fraction permits objective evaluation of possible adulteration of honey with small amounts (7-20%) as well as larger amounts of corn or cane sugar. The present uncertainty

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