926108
(S)-RUCY™-XylBINAP
Takasago
Synonym(s):
RuCl[(S)-daipena][(S)-xylbinap]
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About This Item
Empirical Formula (Hill Notation):
C71H73ClN2O2P2Ru
CAS Number:
Molecular Weight:
1184.82
UNSPSC Code:
12352116
NACRES:
NA.22
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![RuCl2[(S)-(DM-SEGPHOS®)][(S)-DAIPEN]](/deepweb/assets/sigmaaldrich/product/structures/316/926/466dd730-af1f-46d0-a2ac-ed7c8b2abce7/640/466dd730-af1f-46d0-a2ac-ed7c8b2abce7.png)
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Application
(S)-RUCY™-XylBINAP is a ruthenabicyclic complex that shows excellent activity in the asymmetric hydrogenation of ketones.
Legal Information
Product of Takasago.
For research and development purposes only. PCT/JP2010/072838
For research and development purposes only. PCT/JP2010/072838
RUCY is a trademark of Takasago Intl. Corp.
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Product No.
Description
Pricing
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Kazuhiko Matsumura et al.
Journal of the American Chemical Society, 133(28), 10696-10699 (2011-06-17)
A novel ruthenabicyclic complex with base shows excellent catalytic activity in the asymmetric hydrogenation of ketones. The turnover frequency of the hydrogenation of acetophenone reaches about 35,000 min(-1) in the best case, affording 1-phenylethanol in >99% ee. Several aliphatic and
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