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915319

Sigma-Aldrich

Aminosupersilane

Synonym(s):

N-(Adamantan-1-yl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilan-2-amine

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About This Item

Empirical Formula (Hill Notation):
C19H43NSi4
Molecular Weight:
397.89
UNSPSC Code:
12352116
NACRES:
NA.06

form

powder

Quality Level

100

Application

Aminosupersilane has been demonstrated by the MacMillan lab to be a necessary reagent in the dual catalytic nickel/photoredox cross-electrophile coupling of unactivated alkyl chlorides. The increased nucleophilicity of aminosupersilane, as compared to other organosilane reagents, is key to activating the alkyl chloride for chlorine atom abstraction.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Cross-Electrophile Coupling of Unactivated Alkyl Chlorides

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV6211
MKCV3427
MKCW1509
MKCW7710
MKCT3728

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