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915157

Sigma-Aldrich

iPr-PDI

≥95%

Synonym(s):

N,N-Bis(2,6-diisopropylphenyl)perylene-3,4,9,10-bis(dicarboximide)

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About This Item

Empirical Formula (Hill Notation):
C48H42N2O4
CAS Number:
82953-57-9
Molecular Weight:
710.86
UNSPSC Code:
12352101
NACRES:
NA.22

Quality Level

100

Assay

≥95%

form

powder

mp

>300 °C

storage temp.

−20°C

Application

iPr-PDI is a perylene based organic photocatalyst with a variety of demonstrated uses, including the reduction of aryl halides and the iodoperfluoroalkylation of alkenes.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Reduction of aryl halides by consecutive visible light-induced electron transfer processes

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Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Cristian Rosso et al.
Organic letters, 21(13), 5341-5345 (2019-06-30)
Two efficient continuous flow iodoperfluoroalkylation methods are described: using 0.05 mol % perylene diimide (PDI) photocatalyst under 450 nm irradiation or substoichiometric triethylamine under 405 nm irradiation. These methods enable dramatically elevated productivity versus batch processes. The triethylamine-mediated method is
Indrajit Ghosh et al.
Science (New York, N.Y.), 346(6210), 725-728 (2014-11-08)
Biological photosynthesis uses the energy of several visible light photons for the challenging oxidation of water, whereas chemical photocatalysis typically involves only single-photon excitation. Perylene bisimide is reduced by visible light photoinduced electron transfer (PET) to its stable and colored

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