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Key Documents

907847

Sigma-Aldrich

HB(trip)2

≥95%

Synonym(s):

Bis(2,4,6-triisopropylphenyl)borane

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About This Item

Empirical Formula (Hill Notation):
C30H47B
CAS Number:
Molecular Weight:
418.51
UNSPSC Code:
12352101
NACRES:
NA.22

Assay

≥95%

form

solid

mp

109-110 °C

storage temp.

−20°C

Application

HB(trip)2 has been shown by the Hoveyda group to be a useful traceless protecting group for catalytic Z- and E-selective olefin metathesis.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Yucheng Mu et al.
Angewandte Chemie (International ed. in English), 58(16), 5365-5370 (2019-02-13)
An operationally simple in situ protection/deprotection strategy that significantly expands the scope of kinetically controlled catalytic Z- and E-selective olefin metathesis is introduced. Prior to the addition of a sensitive Mo- or Ru-based complex, treatment of a hydroxy- or a

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