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Key Documents

700223

Sigma-Aldrich

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)

97%

Synonym(s):

Mn(dpm)3, Shenvi Hydrogenation Catalyst, Mn(TMHD)3, Tris(dipivaloylmethanato)manganese

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About This Item

Linear Formula:
Mn(C11H19O2)3
CAS Number:
Molecular Weight:
604.74
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Pricing and availability is not currently available.

Quality Level

Assay

97%

form

crystals

reaction suitability

core: manganese
reagent type: catalyst

mp

160-170 °C

SMILES string

CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI

1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;

InChI key

ORZPLLPBZHORSD-LWTKGLMZSA-K

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1 of 4

This Item
102861028310284
particle size

60-80 mesh

particle size

80-100 mesh

particle size

80-100 mesh

particle size

100-120 mesh

form

solid

form

solid

form

solid

form

solid

matrix

HayeSep D

matrix

HayeSep B

matrix

HayeSep A

matrix

HayeSep A

packaging

bottle of 75 cc

packaging

bottle of 75 cc

packaging

bottle of 75 cc

packaging

bottle of 75 cc

parameter

290 °C temp. limit

parameter

190 °C temp. limit

parameter

165 °C temp. limit

parameter

165 °C temp. limit

Application

Catalyst for:
  • Intramolecular Diels-Alder reactions
  • Single electron donor for excess electron transfer studies in DNA
  • Enantioselective synthesis
  • Borylation reactions
  • Hydrohydrazination and hydroazidation
  • Oxidative carbonylation of phenol
Notably, this non-precious metal catalyst can be used to obtain the thermodynamic hydrogenation product of olefins, selectively.

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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