675547

1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate

• Empirical Formula (Hill Notation): C₂₂H₄₀BF₄P₂Rh
• CAS Number: 213343-65-8
• Molecular Weight: 556.21
• UNSPSC Code: 12352005
• PubChem Substance ID: 24885287
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• mp: 152.2-156.3 °C
• functional group: phosphine
• SMILES string: [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C[C@H]2CC[C@H](C)P2CCP3[C@@H](C)CC[C@@H]3C
• InChI: 1S/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m0.../s1
• InChI key: CVUPEPGZCZHSOF-ASDDUFFSSA-N

Description

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:

• Asymmetric hydrogenation

Legal Information

Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves