517763

2,2′-Bipyridine-5,5′-dicarboxylic acid

97%

• Synonym(s): 6,6′-Binicotinic acid
• Empirical Formula (Hill Notation): C₁₂H₈N₂O₄
• CAS Number: 1802-30-8
• Molecular Weight: 244.20
• MDL number: MFCD01318320
• UNSPSC Code: 12352100
• PubChem Substance ID: 24873972
• NACRES: NA.22

Properties

• Assay: 97%
• mp: >360 °C (lit.)
• functional group: carboxylic acid
• SMILES string: OC(=O)c1ccc(nc1)-c2ccc(cn2)C(O)=O
• InChI: 1S/C12H8N2O4/c15-11(16)7-1-3-9(13-5-7)10-4-2-8(6-14-10)12(17)18/h1-6H,(H,15,16)(H,17,18)
• InChI key: KVQMUHHSWICEIH-UHFFFAOYSA-N

Description

General description

2,2′-Bipyridine-5,5′-dicarboxylic acid also known as 6,6′-Binicotinic acid, is a versatile polypyridyl ligand commonly used in the synthesis of metal–organic frameworks.[1]

Application

• Zn-MOFs Containing Pyridine and Bipyridine Carboxylate Organic Linkers and Open Zn2+ Sites: This study discusses the synthesis and characterization of Zinc-based Metal-Organic Frameworks (MOFs) utilizing 2,2′-Bipyridine-5,5′-dicarboxylic acid as a linker, showing potential applications in gas storage and separation (J Kim et al., 2015).


• Ethylene oligomerization in metal organic frameworks bearing nickel (ii) 2, 2′-bipyridine complexes: Reports the use of 2,2′-Bipyridine-5,5′-dicarboxylic acid in Nickel-based MOFs for catalyzing ethylene oligomerization, highlighting the versatility of MOFs in catalysis (MI Gonzalez et al., 2017).


• Two 3-D metal organic frameworks containing 2, 2′-bipyridine-5, 5′-dicarboxylic acid: synthesis, structure, and magnetic properties: Discusses the synthesis and magnetic properties of two 3-D MOFs built with 2,2′-Bipyridine-5,5′-dicarboxylic acid, demonstrating potential for advanced material applications (M Fang et al., 2014).

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves