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472352

Sigma-Aldrich

Poly(4-vinylpyridine)

average Mw ~160,000

Synonym(s):

4-Vinylpyridine polymer, Poly(p -vinylpyridine)

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About This Item

Linear Formula:
(C7H7N)n
CAS Number:
25232-41-1
MDL number:
MFCD00190588
UNSPSC Code:
12162002
PubChem Substance ID:
24870798
NACRES:
NA.23

mol wt

average Mw ~160,000

Quality Level

200

transition temp

Tg 142 °C (onset, annealed)

solubility

DMF, acetic acid and lower alcohols: soluble

InChI

1S/C7H7N/c1-2-7-3-5-8-6-4-7/h2-6H,1H2

InChI key

KFDVPJUYSDEJTH-UHFFFAOYSA-N

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Application

Poly(4-vinylpyridine) can be used:
  • To prepare metal-containing polymer, applicable as nonlinear optically active material.
  • For the removal of perchlorate from an aqueous solution.
It can also be incorporated into active layers of organic solar cells to enhance power conversion efficiency.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW8875
MKCX0519
MKCW5743
MKCR6618
MKCR4568

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4-Vinylpyridine contains 100 ppm hydroquinone as inhibitor, 95%

Sigma-Aldrich

V3204

4-Vinylpyridine

Rita Rodrigues et al.
Materials (Basel, Switzerland), 7(12), 8189-8196 (2014-12-22)
We report on the efficiency improvement of organic solar cells (OPVs) based on the low energy gap polyfluorene derivative, APFO-3, and the soluble C60 fullerene PCBM, upon addition of a residual amount of poly (4-vinylpyridine) (PVP). We find that the
Zenghe Liu et al.
Analytical chemistry, 84(7), 3403-3409 (2012-03-20)
Continuous glucose measurement has improved the treatment of type 1 diabetes and is typically provided by externally powered transcutaneous amperometric sensors. Self-powered glucose sensors (SPGSs) could provide an improvement over these conventionally powered devices, especially for fully implanted long-term applications
Lin-feng Zhou et al.
Journal of chromatography. A, 1256, 15-21 (2012-08-14)
A simple and facile needle-adapter was designed for constructing manual on-line polymer monolith microextraction-high performance liquid chromatography (PMME-HPLC). A capillary poly(4-vinylpyridine-co-ethylene glycol dimethacrylate) [poly(VP-co-EGDMA)] monolith was prepared by in situ polymerization, using 4-vinylpyridine (VP) and ethylene glycol dimethacrylate (EGDMA) as
Jian-Hua Qiu et al.
Journal of colloid and interface science, 354(1), 152-159 (2010-11-19)
Poly(4-vinylpyridine) (P4VP) brushes were grafted onto microporous polysulfone (PSF) membranes via surface-initiated atom transfer radical polymerization (SI-ATRP) and then immobilized copper (II) ions on the modified membrane. Copper-loaded membranes exhibited excellent antibacterial properties with the added advantage of repeated use.
Tobias Miller et al.
Pharmaceutical research, 30(2), 584-595 (2012-11-09)
To gain mechanistic insights into drug loading and lyophilization of polymeric micelles. PEGylated poly-4-(vinylpyridine) micelles were loaded with dexamethasone. Three different methods were applied and compared: O/W emulsion, direct dialysis, cosolvent evaporation. Micellar dispersions with the highest drug load were
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