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464236

Sigma-Aldrich

Zirconium(IV) hydrogenphosphate

Synonym(s):

α-Zirconium phosphate, γ-Zirconium phosphate, Zirconium bis(hydrogen phosphate), Zirconium bis(monohydrogen orthophosphate), Zirconium hydrogen orthophosphate

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About This Item

Linear Formula:
Zr(HPO4)2
CAS Number:
13772-29-7
Molecular Weight:
283.18
EC Number:
237-401-7
MDL number:
MFCD00799602
UNSPSC Code:
12352302
PubChem Substance ID:
24870152
NACRES:
NA.23
grade:
for analytical purposes
form:
powder

grade

for analytical purposes

form

powder

reaction suitability

reagent type: catalyst
core: zirconium

density

3.3 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

[Zr+4].OP([O-])([O-])=O.OP([O-])([O-])=O

InChI

1S/2H3O4P.Zr/c2*1-5(2,3)4;/h2*(H3,1,2,3,4);/q;;+4/p-4

InChI key

QOKYJGZIKILTCY-UHFFFAOYSA-J

Application

Employed in the preparation of layered organic-inorganic, hybrid, conducting materials.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H317

Hazard Classifications

Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV6686
MKCR6049
MKCR6051
MKCP6113
MKCN5551

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Carissa M Vetromile et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(2), 648-652 (2011-01-11)
In this report the photo-physical properties of 9-amino acridine (9AA) associated with αZr-phosphate particles (αZrP) is examined. In ethanol solution 9AA exhibits absorption maxima at 425 nm, 402 nm and 383 nm as well as emission bands centered at 455
Backov, R. et al.
Chemistry of Materials, 9, 1812-1812 (1997)
Angel A Martí et al.
Inorganic chemistry, 49(16), 7298-7303 (2010-08-10)
We studied the structures, luminescence, and self-quenching properties of tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy)(3)(2+)) two-dimensional arrangements within the layers of zirconium phosphate (ZrP). The intercalation of Ru(bpy)(3)(2+) was accomplished using a hydrated form of zirconium phosphate ZrP. Varying the Ru(bpy)(3)(2+)/ZrP intercalation ratio, different
Ajith Pattammattel et al.
Langmuir : the ACS journal of surfaces and colloids, 29(9), 2971-2981 (2013-02-05)
Previously, an ion-coupled protein binding (ICPB) model was proposed to explain the thermodynamics of protein binding to negatively charged α-Zr(IV) phosphate (α-ZrP). This model is tested here using glucose oxidase (GO) and met-hemoglobin (Hb) and several cations (Zr(IV), Cr(III), Au(III)
Mitk'El B Santiago-Berríos et al.
Langmuir : the ACS journal of surfaces and colloids, 28(9), 4447-4452 (2012-02-10)
The direct intercalation reaction of [Co(tpy)(2)](2+) with the highly hydrated θ phase of layered zirconium phosphate (θ-ZrP) resulted in the formation of the oxidized [Co(tpy)(2)](3+) ion within the ZrP material. The X-ray powder diffraction patterns showed that the interlayer distance
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