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435503

Sigma-Aldrich

Poly(propylene glycol)-block-poly(ethylene glycol)-block-poly(propylene glycol)

average Mn ~3,300

Synonym(s):

Pluronic® 31R1, PPG-PEG-PPG

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About This Item

CAS Number:
691397-13-4
MDL number:
MFCD00082049
UNSPSC Code:
12352112
PubChem Substance ID:
24867240
NACRES:
NA.23

form

viscous liquid

Quality Level

100

mol wt

average Mn ~3,300

composition

PEG, 10 wt. %

refractive index

n20/D 1.454

surface tension

34 dyn/cm, 25 °C, 0.1 wt. % in H2O

viscosity

660 cP(25 °C, Brookfield)(lit.)

transition temp

softening point −25 °C
cloud point 25 °C (1 wt. % aqueous solution)

density

1.018 g/mL at 25 °C

HLB

2.0 - 7.0

InChI

1S/C3H6O.C2H4O/c1-3-2-4-3;1-2-3-1/h3H,2H2,1H3;1-2H2

InChI key

RVGRUAULSDPKGF-UHFFFAOYSA-N

General description

Surface activity of the polymer is dependent on the EO/PO ratio. PPG-PEG-PPG exhibits lower foaming, greater defoaming and reduced gelling tendencies relative to Pluronic® surfactants. Terminal secondary hydroxyl groups of PPG-PEG-PPG have lower reactivity and acidity than the primary hydroxyl groups in Pluronic surfactants.

Application

Hard and soft surface cleaners, defoamers in coatings and water treatment. Lubricant in metal working, anti-foaming aid and extender for linear and cross-linked polyesters and polyurethanes.
PPG-PEG-PPG Pluronic® 31R1 can be used as surface cleaners (soft and hard), defoamers in coatings, in water treatment, lubricant in metal working, anti-foaming aid and extender for linear and cross-linked polyesters and polyurethanes.

Features and Benefits

Surface activity is dependent on the EO/PO ratio. Lower foaming, greater defoaming and reduced gelling tendencies relative to Pluronic® surfactants. Terminal secondary hydroxyl groups have lower reactivity and acidity than the primary hydroxyl groups in Pluronic® surfactants.

Legal Information

Pluronic is a registered trademark of BASF

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW3531
MKCQ7591
MKCV3409
MKCS4912
MKCQ1193

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A N Sklifas et al.
Biofizika, 57(2), 317-324 (2012-05-19)
The adsorption abilities of the perfluorocarbon emulsion stabilized by Proxanol 268 were investigated in vitro and in vivo. In vitro, the saturation point for the blood plasma proteins was nearly reached after five minutes of incubation of the emulsion with
Tsz Chung Lai et al.
Colloids and surfaces. B, Biointerfaces, 99, 27-37 (2011-10-18)
Polyplex particles formed with plasmid DNA (pDNA) and Pluronic P85-block-poly{N-[N-(2-aminoethyl)-2-aminoethyl]aspartamide} (P85-b-P[Asp(DET)]) demonstrated highly effective transfection ability compared to PEG-based block cationomer, PEG-b-P[Asp(DET)]. Ternary polyplexes comprising PEG-b-P[Asp(DET)], poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide)-b-P[Asp(DET)] (P(EPE)-b-P[Asp(DET)]) used as an analog of P85-b-P[Asp(DET)], and pDNA were
Xijun Zhang et al.
Journal of Huazhong University of Science and Technology. Medical sciences = Hua zhong ke ji da xue xue bao. Yi xue Ying De wen ban = Huazhong keji daxue xuebao. Yixue Yingdewen ban, 31(6), 842-845 (2011-12-17)
This study examined the effect of P85 (a pluronic block copolymer) and microbubble (MB) ultrasound contrast agents under ultrasound irradiation on gene transfection and expression. The pEGFP plasmids that can encode enhanced green fluorescent protein (pEGFP) served as a report
Houjian Gong et al.
Langmuir : the ACS journal of surfaces and colloids, 28(38), 13590-13600 (2012-09-08)
The block polyethers PEO-PPO-ph-PPO-PEO (BPE) and PPO-PEO-ph-PEO-PPO (BEP) are synthesized by anionic polymerization using bisphenol A as initiator. Compared with Pluronic P123, the aggregation behaviors of BPE and BEP at an air/water interface are investigated by the surface tension and
Jun Song et al.
Water science and technology : a journal of the International Association on Water Pollution Research, 66(4), 792-798 (2012-07-07)
A novel method for the determination of nickel was established by ultrasonic-assisted cloud point extraction (UA-CPE) prior to flame atomic absorption spectrometry (FAAS) analysis. The nickel reacted with N,N'-bis(salicylidene)-1,2-ethanediamine (BSE) to form hydrophobic chelates, which were extracted into the micelles
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