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422843

Sigma-Aldrich

Potassium trifluoromethanesulfonate

98%

Synonym(s):

Potassium triflate, Trifluoromethanesulfonic acid potassium salt

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About This Item

Linear Formula:
CF3SO3K
CAS Number:
Molecular Weight:
188.17
Beilstein:
3727495
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

powder

SMILES string

[K+].[O-]S(=O)(=O)C(F)(F)F

InChI

1S/CHF3O3S.K/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1

InChI key

GLGXXYFYZWQGEL-UHFFFAOYSA-M

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General description

Potassium trifluoromethanesulfonate (KOTf, potassium triflate) is the potassium salt of trifluoromethanesulphonic acid. It has been prepared by neutralizing a warm aqueous solution of trifluoromethanesulphonic acid with potassium carbonate. The structure of siloxane–poly(oxyethylene) hybrids doped with potassium triflate has been investigated.

Application

Potassium trifluoromethanesulfonate (potassium triflate) is suitable as a reagent in the synthesis of guanine-quadruplex hybrid materials by the self-assembly of a guanine-siloxane monomer.
It may be used in the following studies:
  • As a template source for constructing the heterotopic isothiosemicarbazide-based macrocyclic ligand.
  • As a supporting electrolyte in the electrochemical study of evidence for gold anion in ethylenediamine.
  • As a reagent in the synthesis of imidazolium salt, 3-methyl-1-(3R,3aR,6S,6aR)-[6-(benzyloxy)-hexahydrofuro[3,2-b]furan-3-yl]imidazolium trifluoromethanesulfonate.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Local and nanoscopic structure of potassium triflate-doped siloxane-polyoxyethylene ormolytes.
Chaker JA, et al.
Journal of Non-Crystalline Solids, 352(32), 3457-3462 (2006)
Sol-gel selection of hybrid G-quadruplex architectures from dynamic supramolecular guanosine libraries.
Mihai S, et al.
Journal of Materials Chemistry, 20(42), 9443-9448 (2010)
Sara Santiago-Malagón et al.
Biosensors & bioelectronics, 175, 112879-112879 (2020-12-15)
One of the limitations of many skin-patch wearable sensors today is their dependence on silicon-based electronics, increasing their complexity and unit cost. Self-powered sensors, in combination with electrochromic materials, allow simplifying the construction of these devices, leading to powerful analytical
Synthesis of novel chiral imidazolium-based ionic liquids derived from isosorbide and their applications in asymmetric aza Diels-Alder reaction.
Van Buu ON, et al.
Tetrahedron, 65(11), 2260-2265 (2009)
Risa Kawai et al.
Physical chemistry chemical physics : PCCP, 21(45), 25065-25071 (2019-11-07)
The quaternary-ammonium-salt-type amphiphilic compounds 3Cntris-s-Q X (star-type; carbon number between the central amino and ammonium groups s = 2, 3) and 3Cnlin-3-Q X (linear-type; carbon number between the hydrophilic groups s = 3), where n represents the alkyl chain length

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