418080
Pentafluorophenyl diphenylphosphinate
Synonym(s):
FDPP, Diphenylphosphinic acid pentafluorophenyl ester
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About This Item
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form
solid
mp
47-50 °C (lit.)
functional group
fluoro
SMILES string
Fc1c(F)c(F)c(OP(=O)(c2ccccc2)c3ccccc3)c(F)c1F
InChI
1S/C18H10F5O2P/c19-13-14(20)16(22)18(17(23)15(13)21)25-26(24,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChI key
OOWSDKUFKGVADH-UHFFFAOYSA-N
General description
Application
Reagent used in:
- Fmoc solid-phase synthesis
- Synthesis of phorboxazoles, furan-based cyclic homoligopeptides, and ziziphine N
- Synthesis of peptides by solid-phase and solution-phase reactions.[2]
- Preparation of macrocyclic peptide cyclotheonamide B as a thrombin inhibitor.[3]
- Cyclooligomerization of N-methylated-L-valine thiazole amino acid to obtain its cyclic tetramers.[4]
- Macrocyclization of an intermediate for the total synthesis of ziziphine N [5], and for the macrolactamization of precursor in synthesizing cryptophycin D.[6]
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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