414476
Ethyl 3,3-diethoxypropionate
90%, technical grade
Synonym(s):
Malonaldehydic acid ethyl ester diethylacetal
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About This Item
Linear Formula:
(C2H5O)2CHCH2CO2C2H5
CAS Number:
Molecular Weight:
190.24
Beilstein:
1772110
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
technical grade
Assay
90%
form
liquid
refractive index
n20/D 1.411 (lit.)
bp
92-93 °C/13 mmHg (lit.)
density
0.978 g/mL at 25 °C (lit.)
functional group
ester
ether
SMILES string
CCOC(CC(=O)OCC)OCC
InChI
1S/C9H18O4/c1-4-11-8(10)7-9(12-5-2)13-6-3/h9H,4-7H2,1-3H3
InChI key
SIALOQYKFQEKOG-UHFFFAOYSA-N
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General description
Ethyl 3,3-diethoxypropionate participates in the Yb(OTf)3 catalyzed synthesis of dihydropyridines (DHPs).
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
183.2 °F - closed cup
Flash Point(C)
84 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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T Ram Reddy et al.
European journal of medicinal chemistry, 62, 395-404 (2013-02-06)
Montmorillonite K-10 mediated MCR of anilines, arylaldehydes and ethyl-3,3-diethoxypropionate in water afforded 2,6-unsubstituted dihydropyridines depending on the nature of anilines employed. A variety of dihydropyridines were prepared by using this green methodology in good yields and montmorillonite K-10 was found
Construction of a quinoline ring via a 3-component reaction in water: crystal structure analysis and H-bonding patterns of a 2-aryl quinoline.
Reddy TR, et al.
Green Chemistry, 14(7), 1870-1872 (2012)
Ytterbium-catalyzed synthesis of dihydropyridines.
Sueki S, et al.
Tetrahedron Letters, 52(34), 4473-4477 (2011)
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