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328766

Sigma-Aldrich

N-Methyl-N-phenylcarbamoyl chloride

98%

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About This Item

Linear Formula:
C6H5N(CH3)COCl
CAS Number:
4285-42-1
Molecular Weight:
169.61
EC Number:
224-288-4
MDL number:
MFCD00000634
UNSPSC Code:
12352100
PubChem Substance ID:
24859745
NACRES:
NA.22

Assay

98%

bp

280 °C (lit.)

mp

87-90 °C (lit.)

functional group

amine
chloro

storage temp.

2-8°C

SMILES string

CN(C(Cl)=O)c1ccccc1

InChI

1S/C8H8ClNO/c1-10(8(9)11)7-5-3-2-4-6-7/h2-6H,1H3

InChI key

CPGWSLFYXMRNDV-UHFFFAOYSA-N

General description

Solvolyses of N-methyl-N-phenylcarbamoyl chlorides in aqueous binary mixtures of acetone, ethanol, methanol and in water, D2O and 50% D2O-CH3OD were investigated. Iridium-catalyzed annulation of N-methyl-N-phenylcarbamoyl chloride with internal alkyne was reported.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314,H335

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS0072
MKCS7279
MKCK3595
MKCK0458
MKCC0036

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Tomohiro Iwai et al.
Journal of the American Chemical Society, 132(28), 9602-9603 (2010-06-30)
An iridium complex successfully catalyzed the annulation of various N-arylcarbamoyl chlorides with internal alkynes to afford 2-quinolones in good to excellent yields. The present reaction is widely applicable to substrates with various functionalities. An amide-iridacycle complex was isolated, and it
Solvolyses of N-Methyl-N-phenylcarbamoyl Chlorides with Electron Acceptor Substituents in Aqueous Binary Mixtures.
Koo IS, et al
Bull. Korean Chem. Soc., 22(8), 842-846 (2001)

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