32851
trans-1,4-Diaminocyclohexane
≥98.0% (GC)
Synonym(s):
trans-1,4-Cyclohexanediamine
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About This Item
Linear Formula:
C6H10(NH2)2
CAS Number:
Molecular Weight:
114.19
Beilstein:
2801657
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
vapor pressure
18 mmHg ( 87.2 °C)
Assay
≥98.0% (GC)
autoignition temp.
680 °F
expl. lim.
6 %
bp
197 °C (lit.)
mp
68-72 °C (lit.)
SMILES string
N[C@H]1CC[C@H](N)CC1
InChI
1S/C6H14N2/c7-5-1-2-6(8)4-3-5/h5-6H,1-4,7-8H2/t5-,6-
InChI key
VKIRRGRTJUUZHS-IZLXSQMJSA-N
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Application
trans-1,4-Diaminocyclohexane was used in preparation of fully aliphatic polyimides. It was employed as the structure-directing agent in the synthesis of novel two-dimensional layered zinc phosphate.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 2
Flash Point(F)
159.8 °F - closed cup
Flash Point(C)
71 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Hwan-Chul Yu et al.
Journal of nanoscience and nanotechnology, 11(7), 6141-6147 (2011-11-30)
Fully aliphatic polyimides (APIs) were prepared from rel-(1'R,3S5'S)-spiro[furan-3(2H),6'-[3]oxabicyclo[3.2.1]octane]-2,2',4',5(4H)-tetrone (DAn) as unsymmetrical spiro dianhydride, and either cis-trans-1,4-diaminocyclohexane (mix-DACH) or trans-1,4-diaminocyclohexane (trans-DACH) as diamine. Structure of all prepared monomers and polymers was confirmed via 1H-NMR and FT-IR. The solubility, optical transparency, and
Jana Kasparkova et al.
Biochemical pharmacology, 79(4), 552-564 (2009-09-29)
Earlier studies have described promising antitumor activity of a large-ring chelate complex [PtCl(2)(cis-1,4-DACH)] (DACH=diaminocyclohexane). Encouraging antitumor activity of this analogue of cisplatin prompted us to perform studies focused on the mechanistic basis of pharmacological effects of this complex. Four early
Mohammad S Ali et al.
Journal of inorganic biochemistry, 96(4), 452-456 (2003-09-19)
A series of new platinum(II) and platinum(IV) adducts of type [P(II)(cis-1,4-DACH)LCl]NO(3,) where cis-1,4-DACH=cis-1,4-diaminocyclohexane, and L=9-ethylguanine, 1-methylcytosine, adenine, adenosine, cytosine, cytidine, guanine, and [Pt(IV)(cis-1,4-DACH)Ltrans-(X)(2)Cl]NO(3), (where Y=hydroxo or acetato), were synthesized and characterized by elemental analysis, infrared spectroscopy, and 1H and 195Pt
Shalini Balakrishnan et al.
The Journal of organic chemistry, 72(25), 9834-9837 (2007-11-06)
To introduce chirality and functional groups adjacent to guanidiniums to modulate specificity and affinity in recognition, N,N'-bis(Boc)-alpha-guanidino acids were synthesized from alpha-amino acid methyl esters. Protected alpha-guanidino acids coupled to cyclohexylamine and trans-1,4-diaminocyclohexane in good yield and with retention of
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