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309206

Sigma-Aldrich

Rhodium(III) nitrate solution

~10 % (w/w) (Rh in >5 wt. % HNO3)

Synonym(s):

Aqueous rhodium nitrate, Rhodium trinitrate, Rhodium(3+)trinitrate

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About This Item

Linear Formula:
Rh(NO3)3
Molecular Weight:
288.92
MDL number:
MFCD00011201
UNSPSC Code:
12352302
PubChem Substance ID:
24858717
NACRES:
NA.23

form

liquid

Quality Level

100

concentration

≥5.0% (NaOH basis (wt% HNO3, titration))
~10 % (w/w) (Rh in >5 wt. % HNO3)

density

1.41 g/mL at 25 °C

SMILES string

[Rh]

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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Application

  • The saga of rhodium (III) nitrate complexes and their speciation in solution: An integrated experimental and quantum chemical study of rhodium(III) nitrate complexes in solution (SN Vorobyeva et al., 2022).

Signal Word

Danger

Hazard Statements

H272,H290,H314,H331

Hazard Classifications

Acute Tox. 3 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 3 - Skin Corr. 1A

Supplementary Hazards

EUH071

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A new type of intermolecular rhodium(II)-catalyzed [5+3] cycloaddition has been developed. This higher-order cycloaddition between pyridinium zwitterion 1,5-dipole equivalents and enol diazoacetates enables the formation of eight-membered heterocyclic skeletons, which are otherwise difficult to construct. The optimized cycloaddition occurs efficiently under
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Selenium status of the Danish population is below that assumed optimal for the suggested protective effects against chronic diseases, including certain cancers. Fish and shellfish are important dietary sources of selenium in Denmark. We investigated the effect of increased fish
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A regio-, diastereo-, and enantioselective [4+3] cycloaddition between vinylcarbenes and dienes has been achieved using the dirhodium tetracarboxylate catalyst [Rh2(S-BTPCP)4]. This methodology provides facile access to 1,4-cycloheptadienes that are regioisomers of those formed from the tandem cyclopropanation/Cope rearrangement reaction of
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