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298115

Sigma-Aldrich

Potassium dicyanoaurate(I)

98%

Synonym(s):

Gold (I) potassium cyanide, Potassium gold cyanide

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About This Item

Linear Formula:
KAu(CN)2
CAS Number:
Molecular Weight:
288.10
Beilstein:
6235525
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

98%

form

solid

density

3.45 g/mL at 25 °C (lit.)

SMILES string

[K+].N#C[Au-]C#N

InChI

1S/2CN.Au.K/c2*1-2;;/q;;-1;+1

InChI key

OQHPFUBKFKRHKZ-UHFFFAOYSA-N

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General description

Potassium dicyanoaurate, also known as potassium gold cyanide. It is a water-soluble salt that is commonly used in gold electroplating, as a precursor for the synthesis of other gold compounds, and in certain chemical processes.

Application

Potassium dicyanoaurate(I) can be used as:     
  • A precursor in the synthesis of gold nanoparticles and nanowires, which are crucial for applications in electronics, photonics, and catalysis     
  • An electrolyte in the potentiostatic deposition of gold nanowires, which are used in electronics and photonics.    
  • A key component in the production of conductive inks and coatings, which are essential for printed circuit boards and other electronic components.
  • A catalyst in certain chemical reactions.

Pictograms

Skull and crossbonesEnvironment

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Supplementary Hazards

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of gold nanowires with controlled crystallographic characteristics.
Karim S, et al.
Applied Physics. A, Materials Science & Processing, 84(4), 403-407 (2006)
D B Donato et al.
Environment international, 33(7), 974-984 (2007-06-02)
Wildlife deaths associated with cyanide-bearing mine waste solutions have plagued the gold mining industries for many years, yet there is little published data showing the relationship between wildlife mortality and cyanide toxicity. A gap of knowledge exists in monitoring, understanding
M L Wu et al.
Journal of toxicology. Clinical toxicology, 39(7), 739-743 (2002-01-10)
Poisoning after oral ingestion of gold potassium cyanide is rarely reported. A case of suicidal ingestion of gold potassium cyanide (potassium dicyanoaurate; CAS# 13967-50-5) is described. A 27-year-old man attempted suicide by ingesting 5 mL gold potassium cyanide solution. He
Lívia Kocúrová et al.
Talanta, 82(5), 1958-1964 (2010-09-30)
This paper presents a novel approach to dispersive liquid-liquid microextraction (DLLME), based on the use of an auxiliary solvent for the adjustment of density. The procedure utilises a solvent system consisting of a dispersive solvent, an extraction solvent and an
Philip M Yangyuoru et al.
Journal of inorganic biochemistry, 102(3), 576-583 (2008-02-08)
Electrospray ionization spectra of potential cyanide-containing gold-drug metabolites revealed additional, weak, unanticipated peaks at approximately twice the mass of the gold(I) and gold(III) cyanide complexes. The exact masses correspond to proton-linked bimetallic complexes, [H[Au(CN)(m)](2)](-), (m=2,4). Further investigation revealed a total

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