Skip to Content
Merck
All Photos(2)

Key Documents

View All Documentation

297054

Sigma-Aldrich

(Trimethylsilyl)methyllithium solution

1.0 M in pentane

Synonym(s):

(Lithiomethyl)trimethylsilane, Neosilyllithium, [(Trimethylsilyl)methyl]lithium

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
(CH3)3SiCH2Li
CAS Number:
1822-00-0
Molecular Weight:
94.16
Beilstein:
4123225
MDL number:
MFCD00010747
UNSPSC Code:
12352103
PubChem Substance ID:
24857896
NACRES:
NA.22

Quality Level

100

concentration

1.0 M in pentane

bp

35-36 °C

density

0.65 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

[Li]C[Si](C)(C)C

InChI

1S/C4H11Si.Li/c1-5(2,3)4;/h1H2,2-4H3;

InChI key

RJPBNMJOQNIBQW-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Initiates polymerization and copolymerization of cyclosiloxanes. Alkylates metal complexes.

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Hazard Statements

H224,H304,H314,H336,H411

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

EUH014

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

-56.2 °F - closed cup

Flash Point(C)

-49 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Journal of Organometallic Chemistry, 447, 51-51 (1993)
Polym. Bull., 32, 35-35 (1994)
Xiaoyan Tang et al.
Nature communications, 9(1), 2345-2345 (2018-06-13)
Bacterial poly(3-hydroxybutyrate) (P3HB) is a perfectly isotactic, crystalline material possessing properties suitable for substituting petroleum plastics, but high costs and low volumes of its production are impractical for commodity applications. The chemical synthesis of P3HB via ring-opening polymerization (ROP) of

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service