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288403

Sigma-Aldrich

trans-Dichlorobis(triphenylphosphine)platinum(II)

Synonym(s):

trans-Bis(triphenylphosphine)platinum dichloride

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About This Item

Linear Formula:
[(C6H5)3P]2PtCl2
CAS Number:
14056-88-3
Molecular Weight:
790.56
MDL number:
MFCD00010825
UNSPSC Code:
12161600
PubChem Substance ID:
24857337
NACRES:
NA.22

reaction suitability

core: platinum
reagent type: catalyst

SMILES string

Cl[Pt]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.2ClH.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChI key

XAFJSPPHVXDRIE-UHFFFAOYSA-L

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Application

Catalyst for:
  • Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups
  • Alkynylation and hydrogenation reactions
  • Hetero-Diels-Alder/ring-opening reactions
  • Insertion of carbenes into O-H bonds of alcohols
  • Cyclopropanation of olefins
  • Hydroformylation reactions

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 3

Target Organs

Central nervous system,Peripheral nervous system, Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000210779
MKBS1759V
MKBN6160V
MKBF3372
10110JH

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