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265640

Sigma-Aldrich

Tin

powder, <150 μm, 99.5% trace metals basis

Synonym(s):

Sn

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About This Item

Empirical Formula (Hill Notation):
Sn
CAS Number:
7440-31-5
Molecular Weight:
118.71
EC Number:
231-141-8
MDL number:
MFCD00133862
UNSPSC Code:
12161600
PubChem Substance ID:
24856094
NACRES:
NA.22

Quality Level

100

Assay

99.5% trace metals basis

form

powder

reaction suitability

core: tin
reagent type: catalyst

resistivity

11 μΩ-cm, 20°C

particle size

<150 μm

bp

2270 °C (lit.)

mp

231.9 °C (lit.)

density

7.310 g/mL at 25 °C (lit.)

SMILES string

[Sn]

InChI

1S/Sn

InChI key

ATJFFYVFTNAWJD-UHFFFAOYSA-N

Related Categories

General description

Tin is an efficient catalyst for the polycondensation of lactic acid to synthesize poly(lactic acid).

Application

With HCl, reduces a variety of functional groups; stereoselective allylation of carbonyl compounds; in situ generation of tin enolates for directed aldol reactions.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000378205
0000378205
0000312805
0000234192
MKCR3308

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Improving lactic acid melt polycondensation: The role of co-catalyst
Marques DS, et al.
Journal of Applied Polymer Science, 128, 2145-2151 (2013)
P Olmedo et al.
Environment international, 59, 63-72 (2013-06-25)
Although fish intake has potential health benefits, the presence of metal contamination in seafood has raised public health concerns. In this study, levels of mercury, cadmium, lead, tin and arsenic have been determined in fresh, canned and frozen fish and
A Gassenq et al.
Optics express, 20(25), 27297-27303 (2012-12-25)
A surface-illuminated photoconductive detector based on Ge0.91Sn0.09 quantum wells with Ge barriers grown on a silicon substrate is demonstrated. Photodetection up to 2.2µm is achieved with a responsivity of 0.1 A/W for 5V bias. The spectral absorption characteristics are analyzed
D B Shpakovsky et al.
Dalton transactions (Cambridge, England : 2003), 41(48), 14568-14582 (2012-10-12)
Four new organotin(IV) complexes of bis-(2,6-di-tert-butylphenol)tin(IV) dichloride [(tert-Bu-)(2)(HO-Ph)](2)SnCl(2) (1) with the heterocyclic thioamides 2-mercapto-pyrimidine (PMTH), 2-mercapto-4-methyl-pyrimidine (MPMTH), 2-mercapto-pyridine (PYTH) and 2-mercapto-benzothiazole (MBZTH), of formulae {[(tert-Bu-)(2)(HO-Ph)](2)Sn(PMT)(2)} (2), {[(tert-Bu-)(2)(HO-Ph)](2)Sn(MPMT)(2)} (3), {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(PYT)} (4) and {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(MBZT)} (5), have been synthesized and characterized by elemental
Lun Li et al.
Journal of the American Chemical Society, 135(4), 1213-1216 (2013-01-15)
Single-layer single-crystalline SnSe nanosheet with four-atomic thickness of ~1.0 nm and lateral size of ~300 nm is presented here by using a one-pot synthetic method. It is found that 1,10-phenanthroline plays an important role in determining the morphology of the
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