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Key Documents

223050

Sigma-Aldrich

2,4,6-Tri-tert-butylaniline

99%

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About This Item

Linear Formula:
[(CH3)3C]3C6H2NH2
CAS Number:
Molecular Weight:
261.45
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

form

solid

mp

145-147 °C (lit.)

SMILES string

CC(C)(C)c1cc(c(N)c(c1)C(C)(C)C)C(C)(C)C

InChI

1S/C18H31N/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11H,19H2,1-9H3

InChI key

REJGDSCBQPJPQT-UHFFFAOYSA-N

Application

2,4,6-Tri-tert-butylnitrobenzene (bulky amine) was used in the synthesis of monomeric iminophosphorane.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Michael D. Mikoluk et al.
Inorganic chemistry, 38(12), 2791-2801 (2001-10-24)
The substituted-exo-phosphine (X = F, NMe(2), OCH(2)CF(3)) diazaphospholephosphines are exclusively oxidized at this center with either chalcogens (S, Se) or azides to phosphoranodiazaphospholes. Oxidation imparts a dramatic upfield shift of the phosphorus NMR signals and an increase in the (1)J(PC)
João Barroso-Batista et al.
Current biology : CB, 30(6), 1049-1062 (2020-03-07)
Members of the gut microbiota are thought to experience strong competition for nutrients. However, how such competition shapes their evolutionary dynamics and depends on intra- and interspecies interactions is poorly understood. Here, we test the hypothesis that Escherichia coli evolution
Ritesh Ranjan Pal et al.
Cell, 177(3), 683-696 (2019-04-02)
Microbiota and intestinal epithelium restrict pathogen growth by rapid nutrient consumption. We investigated how pathogens circumvent this obstacle to colonize the host. Utilizing enteropathogenic E. coli (EPEC), we show that host-attached bacteria obtain nutrients from infected host cell in a process we
Johana Vásquez-Procopio et al.
Metallomics : integrated biometal science, 12(2), 218-240 (2019-12-05)
Manganese is considered essential for animal growth. Manganese ions serve as cofactors to three mitochondrial enzymes: superoxide dismutase (Sod2), arginase and glutamine synthase, and to glycosyltransferases residing in the Golgi. In Drosophila melanogaster, manganese has also been implicated in the

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