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204161

Sigma-Aldrich

Ammonium perrhenate

99.999% trace metals basis

Synonym(s):

Metaperrhenic acid ammonium salt, Rhenium standard solution

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About This Item

Linear Formula:
NH4ReO4
CAS Number:
Molecular Weight:
268.24
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.999% trace metals basis

form

solid

reaction suitability

reagent type: catalyst
core: rhenium

impurities

≤15.0 ppm Trace Metal Analysis

density

3.97 g/mL at 25 °C (lit.)

SMILES string

N.O[Re](=O)(=O)=O

InChI

1S/H3N.H2O.3O.Re/h1H3;1H2;;;;/q;;;;;+1/p-1

InChI key

XPSXHXWHJAIQJR-UHFFFAOYSA-M

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Application

Reduction of this compound with 2-hydrazinopyridine and triphenylphosphine liads to rhenium(III) organohydrazides which offer potential use as radiopharmaceuticals.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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The detailed syntheses of complexes of the form [Re(O)(X)(RNCH(2)CH(2))(2)N(Me)] (X = Me, Cl, I, R = mesityl, C(6)F(5)), 1-3, incorporating diamidoamine ancillary ligands are described. X-ray crystal structures for the complexes [Re(O)(Me)((C(6)F(5))NCH(2)CH(2))(2)N(Me)], 1a, [Re(O)(I)((C(6)F(5))N CH(2)CH(2))(2)N(Me)], 3a, and [Re(O)(I)((Mes)NCH(2))(2)N(Me)], 3b, are
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We describe a multidentate tripodal ligand in which three pendant arms carrying di(2-picolyl)amine units are linked to the ortho positions of a tris(o-xylyl) scaffold, providing N(CH(2)-o-C(6)H(4)CH(2)N(CH(2)py)(2))(3) (L). Reaction of L with CuCl(2) in the presence of hexafluorophosphate anion afforded blue

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