183644

2-Bromonaphthalene

97%

• Synonym(s): β-Bromonaphthalene, β-Naphthyl bromide, 2-Naphthyl bromide
• Empirical Formula (Hill Notation): C₁₀H₇Br
• CAS Number: 580-13-2
• Molecular Weight: 207.07
• Beilstein: 1858110
• EC Number: 209-452-5
• MDL number: MFCD00004051
• UNSPSC Code: 12352100
• PubChem Substance ID: 24851065
• NACRES: NA.22

Properties

• Assay: 97%
• form: solid
• impurities: ≤3% 1-bromonaphthalene
• bp: 281-282 °C (lit.)
• mp: 52-55 °C (lit.)
• solubility: methanol: soluble 50 mg/mL, clear, colorless to yellow
• functional group: bromo
• SMILES string: Brc1ccc2ccccc2c1
• InChI: 1S/C10H7Br/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H
• InChI key: APSMUYYLXZULMS-UHFFFAOYSA-N
• Gene Information: human ... CYP2A6(1548) ; mouse ... Cyp2a5(13087)

Description

General description

Reaction of 2-bromonaphthalene with cuprous cyanide in N-methylpyrrolidone has been investigated. Nanosecond time-resolved resonance Raman spectra of the T₁→T_n transition of 2-bromonaphthalene in methanol solvent has been investigated.

Application

2-Bromonaphthalene was used in the synthesis of biaryls via Suzuki cross coupling reaction in water under microwave irradiation.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H302,H319
• Precautionary Statements: P301 + P312 + P330 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): 235.4 °F - closed cup
• Flash Point(C): 113 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves